(Me2NCH(η(5)-C5H4)Fe(CO)2I)2 | 246230-85-3

• 英文名称: (Me2NCH(η(5)-C5H4)Fe(CO)2I)2
• CAS: 246230-85-3
• 化学式: C₂₀H₂₂Fe₂I₂N₂O₄
• 分子量: 719.909
• InChiKey: LPKOVYXYOCTSMT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (Me2NCH(η(5)-C5H4)Fe(CO)2)2 、 碘 以 二氯甲烷 为溶剂， 以45%的产率得到(Me2NCH(η(5)-C5H4)Fe(CO)2I)2
  参考文献：
  名称：

  Synthesis of hexametallic CH2{(η5-C5H4)Fe(CO)2SnPh2(η5-C5H5)Fe(CO)2}2

  摘要：

  The hexametallic complex CH2{(eta(5)-C5H4)Fe(CO)(2)SnPh2(eta(5)-C5H5)Fe(CO)(2)}(2) (3), has been synthesised and its crystal structure determined to exemplify Fe-Sn-Fe bond formation in related polymer systems. A potentially similar product was anticipated from the reaction of [(CH2{(eta(5)-C5H4)Fe(CO)(2)}(2)](2-) and Ph2SnCl2, however the cyclic complex {CH2(eta(5)-C5H5)Fe(CO)(2)}(2)SnPh2 (7), was isolated. The crystal structure of complex 7 shows that there is considerable strain in the ring containing the metal atoms. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00043-2