[((3-tert-butyl-2-oxy-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane)ZnCl] | 247039-13-0

• 英文名称: [((3-tert-butyl-2-oxy-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane)ZnCl]
• CAS: 247039-13-0
• 化学式: C₂₂H₂₉ClN₄OZn
• 分子量: 466.341
• InChiKey: CFTOLWOOEGWGFJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  zinc(II) chloride dihydrate 、 (3-tert-butyl-2-hydroxy-5-methylphenyl)bis(3,5-dimethylpyrazolyl)methane 在 NaOMe 作用下， 以 乙腈 为溶剂， 以65%的产率得到[((3-tert-butyl-2-oxy-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane)ZnCl]
  参考文献：
  名称：

  Synthesis and Characterization of Pseudotetrahedral N₂O and N₂S Zinc(II) Complexes of Two Heteroscorpionate Ligands:  Models for the Binding Sites of Several Zinc Metalloproteins

  摘要：

  Nine new pseudotetrahedral Zn(II) complexes of the heteroscorpionate ligands (3-tert-butyl-2-hydroxy(or thio)-5-methylphenyl)bis(3,5-dimethylpyrazolyl)methane, L1OH or L2SH, have been prepared and characterized (in most cases crystallographically). Complexes isolated include [(L1O)ZnCl]. [(L1O)ZnI], [(L1OH)ZnI2]. [(L1O)-ZnCH3,] [(L1O)ZnOAc], [(L1O)ZnSPh], [(L1O)ZnSBz], [(L2S)ZnCH3], [(L2S)ZnSPh], and [(L2S)(2)Zn]. In conjunction with the widely studied tris(pyrazolyl)borates this new series of heteroscorpionates provides a set of isolobal and isoelectronic ligands differing in donor set, i.e. N-3, N2O, and N2S. Preliminary reactivity studies with HX species, Mel, or trimethyl phosphate suggest differences between the three sets of ligands.

  DOI：

  10.1021/ic990233v