[(scandium)N(SiMe2(2-methylfuryl))Cl2]2 | 1226953-73-6

• 英文名称: [(scandium)N(SiMe2(2-methylfuryl))Cl2]2
• CAS: 1226953-73-6
• 化学式: C₂₈H₄₄Cl₄N₂O₄Sc₂Si₄
• 分子量: 816.734
• InChiKey: USEDDDHQWNIOBC-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Li[(1,3-bis(2-methylfuryl)-1,1,3,3-tetramethyldisilazide)] 、 氯化钪 以 甲苯 为溶剂， 以60%的产率得到[(scandium)N(SiMe2(2-methylfuryl))Cl2]2
  参考文献：
  名称：

  Group 3 complexes incorporating (furyl)-substituted disilazide ligands

  摘要：

  A series of mono-and bis-amide scandium and yttrium compounds incorporating the furyl-substituted disilazide ligand, [N{SiMe2R}(2)] {i} (where R = 2-methylfuryl) have been synthesized. The compounds Sc{i}Cl-2 (1), Sc{i}(CH2SiMe3)(2) (2) and Sc{i}(OAr)(2) (3) were made from suitable scandium starting materials employing either a salt metathesis protocol with Li{i} or via protonolysis of Sc-C bonds by the neutral amine H{i}. The thermally unstable bis-alkyl yttrium compound, 'Y{i}(CH2SiMe3)(2)' was isolated as the bis-THF adduct (4) and the bis-aryloxide Y{i}(OAr)(2) (5) was synthesized by elimination of LiOAr from Y(OAr)(3). The bis-amide complex Y{i}(2)Cl (6) and conversion to a rare example of an yttrium benzyl compound Y{i}(2)(CH2Ph) (7) are described. The yttrium cation, [Y{i}(2)](+), was synthesized by benzyl abstraction from 7 using B(C6F5)(3). Structural characterization of representative examples show variation in the coordination modes for amide ligand {i}, differing primarily in the number of furyl groups that coordinate to the metal, with examples in which zero, one or two M-O-furyl bonds are present. Preliminary investigation in two areas of catalysis are presented. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.09.051