tBuAl(AltBu2)2(pinacolate)3 | 1018449-55-2

• 英文名称: tBuAl(AltBu2)2(pinacolate)3
• 英文别名: tBuAl(AltBu2)2(2,3-dimethylbutane-2,3-diolate)3
• CAS: 1018449-55-2
• 化学式: C₃₀H₆₃Al₃O₆
• 分子量: 600.771
• InChiKey: XDTNWYLLEDEPOG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  频哪醇 、 (t)Bu3Al*OEt2 以 甲苯 为溶剂， 以99%的产率得到tBuAl(AltBu2)2(pinacolate)3
  参考文献：
  名称：

  Synthesis and structural characterisation of alkylaluminium and alkylgallium pinacolates

  摘要：

  The influence of the steric repulsion of ligands on the structure of alkylaluminium and alkylgallium 2,3-dimethylbutane-2,3-diolates (pinacolates) has been studied. Reaction of Me3Al and pinacol afforded the compound Me5Al3[OC(CH3)(2)C(CH3)(2)O](2) (1) possessing two diolate liQands. The treatment of pinacol with the more sterically hindered (Bu3Al)-Bu-t resulted in the formation of aluminium tripinacolate (Bu3Al3)-Bu-t[OC(CH3)(2)C(CH3)(2)O](3) (2) as the only product. In contrast, the reaction of the less reactive (Bu3Ga)-Bu-t with pinacol stopped at the stage of the compound (Bu3Ga2)-Bu-t[OC(CH3)(3)C(CH3)(2)O] [OC(CH3)(3)C(CH3)(2)OH] (3), which is an intermediate product of the reaction of 1,2-diols with group 13 trialkyls. Compounds 1, 2 and 3 were crystallographically characterised. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.11.027