di-μ-chloro-bis(chloro[2-(pyrazol-1-yl-κN)-2-thiazoline-κN])copper(II) | 886227-45-8

• 英文名称: di-μ-chloro-bis(chloro[2-(pyrazol-1-yl-κN)-2-thiazoline-κN])copper(II)
• 英文别名: [CuCl(PyTn)]2(μ-Cl)2
• CAS: 886227-45-8
• 化学式: C₁₂H₁₄Cl₄Cu₂N₆S₂
• 分子量: 575.319
• InChiKey: LJUYIUVHGNMWBS-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2-(pyrazol-1-yl)-2-thiazoline 以 乙醇 为溶剂， 以88%的产率得到di-μ-chloro-bis(chloro[2-(pyrazol-1-yl-κN)-2-thiazoline-κN])copper(II)
  参考文献：
  名称：

  Structural characterization of a thiazoline-pyrazole ligand and its complexes with cobalt(II) and copper(II)

  摘要：

  The structural characterization of 2-(pyrazol-1-yl)-2-thiazoline (PyTn) is reported. The complexes dichlorobis[2-(pyrazol-l-yl-kappa N)-2thiazoline-kappa N] cobalt(II)-water- (1/2) (1) and di-mu-chloro-bis{chloro(2-(pyrazol-1-yl-kappa N) -2-thiazoline-kappa N]}copper(II) (2) have been isolated and characterized through elemental analysis, IR, UV-Vis-NIR diffuse reflectance, X-ray diffraction and magnetic susceptibility, as well as, in the case of 2, by means of EPR. The environment around cobalt atom in I may be described as a distorted octahedron with the metallic atom coordinated to two thiazoline nitrogen atoms [Co-N(1) = 2.097(2) angstrom], two pyrazole nitrogen atoms (CoN(3) = 2.157(2) angstrom] and two chloride ions [Co-Cl(1) = 2.472(1) angstrom]. With regard to 2, it can be said that its structure consists of dimeric [Cu2Cl4L2] molecules in which copper ions are bridged by two chloro ligands. The geometry about each copper ion approximates to a distorted square pyramid with each copper atom coordinated to one thiazoline nitrogen atom [Cu-N(1) = 2.012(2) angstrom], one pyrazole nitrogen atom [Cu-N(3) = 1.995(2) angstrom], one terminal chloro ligand [Cu-Cl(1) = 2.254(1) angstrom] and two bridging chloro ligands [Cu-Cl(2) = 2.218(1) angstrom, Cu-Cl(2a) = 2.906(1) angstrom]. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.09.028