[Cu(N,N-bis(2-benzylmercaptoethyl)-N-(3-benzylmercaptopropyl)amine)]BF4 | 1267687-68-2

• 英文名称: [Cu(N,N-bis(2-benzylmercaptoethyl)-N-(3-benzylmercaptopropyl)amine)]BF4
• CAS: 1267687-68-2
• 化学式: BF₄*C₂₈H₃₅CuNS₃
• 分子量: 632.141
• InChiKey: UPHNJQUPALQECJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I)tetrafluoroborate 、 N,N-bis(2-benzylmercaptoethyl)-N-(3-benzylmercaptopropyl)amine 以 乙腈 为溶剂， 以92%的产率得到[Cu(N,N-bis(2-benzylmercaptoethyl)-N-(3-benzylmercaptopropyl)amine)]BF4
  参考文献：
  名称：

  Copper(I) complexes of N-centered aliphatic tripodal trithioether ligands – Adjustment of complex geometry by variation of spacer lengths

  摘要：

  A series of novel aliphatic tripodal trithioether ligands 4-6 differing in the lengths of the alkyl chains between central nitrogen atom and sulfur donor function has been synthesized. The neutral ligands 4-6 react with copper(I) under formation of the mononuclear complexes 7-9 featuring exclusive coordination of the metal center by the tertiary amine and the three thioether donor functions of the tripodal ligand. Molecular structures of 7 and 9 show a direct influence of the spacer lengths between central and terminal donor functions on the geometry of the tetracoordinated complex cations. Substitution of one ethylene by a propylene spacer leads to a larger bite angle between the amine and thioether donor functions and effects a tetrahedral distortion for the complex cation in 7. For the copper(I) compound 9 with a ligand possessing exclusively propylene spacers this effect is increased leading to a tetrahedral geometry of the complex cation. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.10.008