trans-[PtCl(NH2C6H11)(NHC(CH3)NHC6H11)2](1+) | 1220561-64-7

• 英文名称: trans-[PtCl(NH2C6H11)(NHC(CH3)NHC6H11)2](1+)
• CAS: 1220561-64-7
• 化学式: C₂₂H₄₅ClN₅Pt
• 分子量: 610.166
• InChiKey: AHZAFWMDKPTTME-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  环己胺 、 bis(acetonitrile)dichloroplatinum(II) 以 乙腈 为溶剂， 生成 trans-[PtCl(NH2C6H11)(NHC(CH3)NHC6H11)2](1+)
  参考文献：
  名称：

  Reactivity of trans-[PtCl2(NCMe)2] with cycloaliphatic amines: An ESI and NMR study. X-ray structure of

  摘要：

  The reactivity of the cyclic primary aliphatic amines cyclopropyl-, cyclopentyl-and cyclohexylamine with cis- and trans-[PtCl2(NCMe)(2)], under the same experimental conditions, is compared. Whereas cis-[PtCl2(NCMe)(2)] yields the neutral diamidine compounds, the reactions with trans-[PtCl2(NCMe)(2)] take place either with addition or substitution processes yielding the neutral diamidine complexes trans-[PtCl2(Amidine)(2)], the monocationic trans-[PtCl(Amine)(Amidine)(2)]Cl and the dicationic trans-[Pt(Amine)(2)(Amidine)(2)]Cl-2 salts. An NMR and ESI study indicate that the main species formed is the monocationic trans-[PtCl(Amine)(Amidine)(2)] Cl complex.The X-ray structure of trans-[PtCl2{N(H)=C(CH3)NHCHCH2CH2}(2)] is reported and its supramolecular arrangement is described. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.09.012