[(1,2-bis(2-methylphenylimino)acenaphthene)Mo(CO)3(η3-C3H4-Me-2)]PF6 | 1140479-38-4

• 英文名称: [(1,2-bis(2-methylphenylimino)acenaphthene)Mo(CO)3(η3-C3H4-Me-2)]PF6
• CAS: 1140479-38-4
• 化学式: C₃₃H₂₇MoN₂O₃*F₆P
• 分子量: 740.493
• InChiKey: JBIQNUDRTMKGRM-RPJCWBBWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,2-bis[(2-methylphenyl)imino]acenaphthene 、 [Mo(CO)3(THF)2(η3-C4H7)]PF6 以 二氯甲烷 为溶剂， 生成 [(1,2-bis(2-methylphenylimino)acenaphthene)Mo(CO)3(η3-C3H4-Me-2)]PF6
  参考文献：
  名称：

  Synthesis and structure of new cationic methallyl molybdenum(II) complexes supported by α-diimine ligands

  摘要：

  Cationic complexes [Mo(eta(3)-C3H4-Me-2)(N-N)(CO)(3)]+PF6-, {N-N = bipy (2); DAD (Ar-N = C(Me)-C(Me)= N-Ar: Ar = o-Me-C6H4 (3). 2,6-Me-2-C6H3 (4): Ar-BIAN (Ar = o-Me-C6H4 (5), Ar = iPr(2)-C6H3 (6)}; were synthesized by treating the compound Mo(CO)(3)(p-xylene) with the allyloxyphosphonium salt in situ in presence of diimine ligand. Complex 4 was characterized by single crystal X-ray diffraction. The solid state structure of the complexes revealed a preference for the more unsymmetrical axial isomer. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.11.050