[TlMe2(3-hydroxypicolinic acid(1-))] | 1021494-57-4

• 英文名称: [TlMe2(3-hydroxypicolinic acid(1-))]
• CAS: 1021494-57-4
• 化学式: C₁₆H₂₀N₂O₆Tl₂
• 分子量: 745.111
• InChiKey: XDGMSXIIVJCPNB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-羟基-2-吡啶甲酸 、 dimethylthallium(III) iodide 以 甲醇 、 水 为溶剂， 以70%的产率得到[TlMe2(3-hydroxypicolinic acid(1-))]
  参考文献：
  名称：

  Dimethylthallium(III) complexes with picolinic acid and its hydroxyl derivatives

  摘要：

  The reaction of dimethylthallium(III) hydroxide with picolinic acid (Hpic), 3-hydroxypicolinic acid (H(2)3hpic) and 6-hydroxypicolinic acid (H(2)6hpic) in an aqueous/methanol mixture afforded the complexes [TlMe2(pic)] (1), [TlMe2(H3hpic)] (2) and [TlMe2(H6hpic)] (3), respectively. Complex 3', [NaTlMe2(6hpic)(2)](n), was obtained as a minor product from a methanolic solution of 3. Compounds 1-3 were characterized by IR and Raman spectroscopy and, in the cases of 1, 2 and Y, by single-crystal X-ray diffraction. Complex 3' is the first example of an H6hpic(-) heterobimetallic compound to be isolated. The H-1 and C-13 NMR spectra of 1 and 2 are also discussed. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.12.021