[(2,6-((i-Pr)2PO)C6H3(CHN(m-ClC6H4)))PdCl] | 1178971-33-9

• 英文名称: [(2,6-((i-Pr)2PO)C6H3(CHN(m-ClC6H4)))PdCl]
• CAS: 1178971-33-9
• 化学式: C₁₉H₂₂Cl₂NOPPd
• 分子量: 488.69
• InChiKey: TYGHQJIHNDXUML-ORKRDPRMSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯二异丙基膦 、 m-Hydroxybenzylidenamino-m-chlorbenzol 、 palladium dichloride 在 (C₂H₅)3N 作用下， 以 甲苯 为溶剂， 以47%的产率得到[(2,6-((i-Pr)2PO)C6H3(CHN(m-ClC6H4)))PdCl]
  参考文献：
  名称：

  Facile synthesis of achiral and chiral PCN pincer palladium(II) complexes and their application in the Suzuki and copper-free Sonogashira cross-coupling reactions

  摘要：

  Five non-symmetrical PCN pincer palladium(II) complexes [PdCl{C6H3-2-(CH=NR)-6-(OPR'(2))}] (R = m-ClC6H4, R' = Ph (2a); R = Ph, R' = Ph (2b); R = i-Pr, R' = Ph (2c); R = m-ClC6H4, R' = i-Pr (2d); R = (S)-1-phenylethyl, R' = Ph (2e)) have been easily prepared in only two steps from readily available m-hydroxybenzaldehyde and characterized by HRMS, H-1 NMR, C-13 NMR, P-31 NMR and IR spectra. The molecular structures of 2a and 2b have been further determined by X-ray single-crystal diffraction. The obtained Pd complexes were found to be effective catalysts for the Suzuki and copper-free Sonogashira cross-coupling reactions which could be carried out in the undried solvent under air. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.04.002