[TiCp*(sal)(salH)]2 | 918496-86-3

• 英文名称: [TiCp*(sal)(salH)]2
• CAS: 918496-86-3
• 化学式: C₄₈H₄₈O₁₂Ti₂
• 分子量: 912.662
• InChiKey: PRGINAUEUCEWNZ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Rh(OH)(cod)]2 、 [TiCp*(sal)(salH)]2 以 二氯甲烷 为溶剂， 以65%的产率得到[TiCp*(sal)2Rh(COD)]
  参考文献：
  名称：

  Synthesis and reactivity of heterometallic RhO–M (M=Si, Ti) complexes

  摘要：

  The titanium salycilate complex [Cp*Ti(sal)(salH)] 1 (salH(2), = salycilic acid) was synthesised by reacting Cp*TiMe3 and salycilic acid. The molecular structure of 1 studied by X-ray shows it to be dinuclear with a carboxylate group acting as a bridge ligand. [Rh(mu-OH)COD](2) reacts with 1 to yield the bimetallic complex 2, or with the siloxanodiol (HOSiPh)(2)O to yield the bimetalic bis-siloxide Rh complex 3. Carbon monoxide displaces COD in 2 and 3 to give the carbonylic complexes 4 and 5 respectively. Complex 4 can also be prepared from 2 and [Rh(acac)(CO)(2)]. Compounds 2, 3, 4 and 5 can be envisaged as models of Rh complexes anchored on titania or silica. The catalytic performance of heterometallic complexes is studied in the CO hydrogenation reaction and compared to rhodium-based (Rh-based) catalysts prepared by impregnation from Rh(NO3)(3) or [Rh(acac)(CO)2] showing higher yields to oxygenated products. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.11.032
• 作为产物：
  描述：

  carbanide,cyclopenta-1,3-diene,titanium(4+) 、 水杨酸 以 甲苯 为溶剂， 以76%的产率得到[TiCp*(sal)(salH)]2
  参考文献：
  名称：

  Synthesis and reactivity of heterometallic RhO–M (M=Si, Ti) complexes

  摘要：

  The titanium salycilate complex [Cp*Ti(sal)(salH)] 1 (salH(2), = salycilic acid) was synthesised by reacting Cp*TiMe3 and salycilic acid. The molecular structure of 1 studied by X-ray shows it to be dinuclear with a carboxylate group acting as a bridge ligand. [Rh(mu-OH)COD](2) reacts with 1 to yield the bimetallic complex 2, or with the siloxanodiol (HOSiPh)(2)O to yield the bimetalic bis-siloxide Rh complex 3. Carbon monoxide displaces COD in 2 and 3 to give the carbonylic complexes 4 and 5 respectively. Complex 4 can also be prepared from 2 and [Rh(acac)(CO)(2)]. Compounds 2, 3, 4 and 5 can be envisaged as models of Rh complexes anchored on titania or silica. The catalytic performance of heterometallic complexes is studied in the CO hydrogenation reaction and compared to rhodium-based (Rh-based) catalysts prepared by impregnation from Rh(NO3)(3) or [Rh(acac)(CO)2] showing higher yields to oxygenated products. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.11.032