| 208576-85-6

• CAS: 208576-85-6
• 化学式: C₁₈H₃₂ClCuN₄*F₆P
• 分子量: 548.442
• InChiKey: NFQZNUYDXSIKLL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 sodium N,N-(diethylamino)diazen-1-ium-1,2-diolate 以 甲醇 为溶剂， 以69%的产率得到
  参考文献：
  名称：

  单-与所述亲核复合体[等的二齿配位2 N（N 2 Ò 2）] -四齿配体的铜（II）络合物

  摘要：

  Copper(II) complexes of [Et2N(N2O2)](-) with tetradentate, tripodal ligands composed of 1,4,7-triazacyclononanes with pyridine (L-Py), amide (L-HAmH) Or phenolate (L-R2, R = Me, or Bu-t phenolate substituents) groups as the fourth donor were prepared and characterized by spectroscopic and X-ray crystallographic methods. Bidentate O,O-coordination of [Et2N(N2O2)](-) was observed in the complexes supported by L-Py and L-HAmH, but the stronger phenolate donor in L-R2 induced novel monodentate coordination via the terminal oxygen atom, defined by X-ray crystallography for R = Bu-t. Comparison of the bonding parameters of [Et2N(N2O2)](-) when bound bidentate vel sus when bound monodentate revealed subtle but significant differences in the N-O distances. The amount and rate of nitric oxide (NO) release from the compounds was measured using a chemiluminescence detection method. Despite the differences in [Et2N(N2O2)](-) structural parameters resulting from the divergent coordination modes, insignificant variation of the rates of NO release therefrom were found.

  DOI：

  10.1039/a800561c
• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 1,4-diisopropyl-7-(2-methylpyridyl)-1,4,7-triazacyclononane 、 copper dichloride 以 甲醇 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  单-与所述亲核复合体[等的二齿配位2 N（N 2 Ò 2）] -四齿配体的铜（II）络合物

  摘要：

  Copper(II) complexes of [Et2N(N2O2)](-) with tetradentate, tripodal ligands composed of 1,4,7-triazacyclononanes with pyridine (L-Py), amide (L-HAmH) Or phenolate (L-R2, R = Me, or Bu-t phenolate substituents) groups as the fourth donor were prepared and characterized by spectroscopic and X-ray crystallographic methods. Bidentate O,O-coordination of [Et2N(N2O2)](-) was observed in the complexes supported by L-Py and L-HAmH, but the stronger phenolate donor in L-R2 induced novel monodentate coordination via the terminal oxygen atom, defined by X-ray crystallography for R = Bu-t. Comparison of the bonding parameters of [Et2N(N2O2)](-) when bound bidentate vel sus when bound monodentate revealed subtle but significant differences in the N-O distances. The amount and rate of nitric oxide (NO) release from the compounds was measured using a chemiluminescence detection method. Despite the differences in [Et2N(N2O2)](-) structural parameters resulting from the divergent coordination modes, insignificant variation of the rates of NO release therefrom were found.

  DOI：

  10.1039/a800561c