[CuCl2(1,3-bis(2-pyridylthio)propane)]2 | 777860-63-6

• 英文名称: [CuCl2(1,3-bis(2-pyridylthio)propane)]2
• CAS: 777860-63-6
• 化学式: C₂₆H₂₈Cl₄Cu₂N₄S₄
• 分子量: 793.703
• InChiKey: ZRKBLNYXRWUBEW-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,3-双(2-吡啶硫代)丙烷 、 copper(l) chloride 在 O₂ 作用下， 以 氯仿 、 乙腈 为溶剂， 生成 [CuCl2(1,3-bis(2-pyridylthio)propane)]2
  参考文献：
  名称：

  A novel bimetallic macrocyclic CuII complex with a flexible pyridyl dithioether ligand

  摘要：

  A novel Cu-II complex with a pyridyl dithioether ligand [Cu(L)Cl-2](2) (1) [L = 1,3-bis(2-pyridylthio)propane], has been synthesized and structurally characterized by X-ray diffraction analysis. Complex 1 crystallizes in monoclinic system, space group P2(1)/n, a = 14.208(5), b = 8.586(3), c = 14.309(5) Angstrom, beta = 116.787(6)degrees and Z = 4. In this complex, the ligand adopts N,N-bidentate coordination mode with two pyridine nitrogens in syn-form, and two ligands equivalently bridge two Cu-II centers to form a 20-membered macrometallacyclic structure. Each Cu-II center is four-coordinated by two nitrogen donors from two distinct L ligands and two chloride anions in trans-form. In addition, the weak C-H-. . . Cl hydrogen-bonding interactions link these dimeric units into a three-dimensional supramolecular architecture. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2004.01.013