[Rh(I)(trifluoroacetylacetonate)(1,5-cyclooctadiene)] | 32610-46-1

• 英文名称: [Rh(I)(trifluoroacetylacetonate)(1,5-cyclooctadiene)]
• 英文别名: Rh(CH₃COCHCOCF₃)(1,5-cyclooctadiene)；Rh(CH₃COCHCOCF₃)(COD)
• CAS: 32610-46-1
• 化学式: C₁₃H₁₆F₃O₂Rh
• 分子量: 364.17
• InChiKey: SFABASSLZJHWIQ-GCOBPYNFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Rh(I)(trifluoroacetylacetonate)(1,5-cyclooctadiene)] 、 四苯硼钠 以 乙腈 为溶剂， 以74.1%的产率得到Rh(1+)(1,5-cyclooctadiene)(η6-C6H5B(1-)Ph3)
  参考文献：
  名称：

  A novel reaction producing the rhodium(I) complexes with π-coordinated tetraphenylborate anion, (π-PhBPh3)−. X-ray study of [Rh(PPh3)2(π-PhBPh3)]

  摘要：

  Treating the complexes [Rh(TFA)(PPh3)(2)], [Rh(HFA)(PPh3)(2)], and [Rh(TFA)(Cod)] (TFA - trifluoroacetylacetonate, HFA - hexafluoroacetylacetonate, Cod - 1,5 cyclooctadiene) with an excess of NaBPh4 in acetonitrile yields the rhodium(I) complexes with coordinated [BPh4](-) anion, [Rh(PPh3)(2)(pi-PhBPh3)] center dot 2MeCN (I) and [Rh(Cod)(pi-PhBPh3)] (II). The reactions present a new example of (beta-diketonate ligand replacement. The H-1, P-31, and B-11 NMR spectra of I and II are discussed. [Rh(PPh3)(2)(pi-PhBPh3)] has been characterized by single crystal X-ray analysis. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.06.057