rac-diphenyl[(N,N,N-trimethylaminomethylferrocenyl)iodide]stibine | 911852-61-4

• 英文名称: rac-diphenyl[(N,N,N-trimethylaminomethylferrocenyl)iodide]stibine
• 英文别名: diphenyl[2-(N,N,N-trimethylaminiummethyl)ferrocenyl]antimony iodide
• CAS: 911852-61-4
• 化学式: C₂₆H₂₉FeNSb*I
• 分子量: 660.024
• InChiKey: VOWZXBOVUOOWJC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  rac-diphenyl[(N,N,N-trimethylaminomethylferrocenyl)iodide]stibine 在 K₂CO₃ 作用下， 以 甲醇 、 乙腈 为溶剂， 以38%的产率得到diphenyl(2-methoxymethylferrocen-1-yl)stibine
  参考文献：
  名称：

  1,2-二取代二茂铁基锑的合成、表征和晶体结构

  摘要：

  合成了含有 -CH2OR 悬臂的新型 1,2-二茂铁基锑，并通过各种光谱和分析方法对其进行了表征。用甲醇亲核取代外消旋二苯基[(2-三甲基氨甲基二铁-1-基)]碘化锑，生成化合物 Fc(CH2OMe)SbPh2 (1)。乙酸酐对二苯基（2-二甲基氨基甲基二茂铁-1-基）二苯基锑的乙酰化得到化合物 Fc(CH2OCOCH3)SbPh2 (2)，进一步与氢氧化钠反应得到醇 Fc(CH2OH)SbPh2 (3)。锑1、2和3的分子结构通过X射线晶体学确定。含有 -CH2OR 臂的异双金属化合物均未在固态下显示出高价相互作用。相比之下，在具有 -CH2NR2 悬臂的二茂铁基锑中发现了高价相互作用。图形摘要综合，

  DOI：

  10.1515/znb-2012-0107

文献信息

• Preparation of new 1,2-disubstituted ferrocenyl stibine derivatives containing ether/thioether pendant arm from a quaternary ferrocenyl ammonium salt
  作者：D. Pérez、P. Sharma、A. Cabrera、N. Rosas、I. Arellano、A. Toscano、S. Hernández

  DOI：10.1016/j.poly.2009.06.067

  日期：2009.9

  New 1,2-disubstituted ferrocenyl stibines viz. containing -CH2OR or -CH2SR pendant arm at the orthoposition have been synthesized and characterized by various physicochemical methods. These new ferrocenylstibines were prepared by the nucleophilic substitution reaction of diphenyl[(N,N,N-trimethylaminomethylferrocenyl)iodide]stibine by different phenols and thiol viz. o-salicyldehyde, m-hydroxyacetaphenone, o-hydroxyaceta-phenone and furan-2 ylmethylthiol. Molecular structures of stibines (2),(3),(4) and (5) have been determined by X-ray crystallography. Molecular structures show that none of these heterobimetallic compounds possess hypervalent interaction in the solid state. This type of interaction was found in similar compounds with CH2NR2 pendant arm. (C) 2009 Elsevier Ltd. All rights reserved.
• New 1,2-disubstituted ferrocenyl stibines containing N-heterocyclic pendant arm: Sb–N hypervalent compounds
  作者：A.M. Ortiz、P. Sharma、D. Pérez、Noé Rosas、A. Cabrera、L. Velasco、A. Toscano、S. Hernández

  DOI：10.1016/j.jorganchem.2009.01.051

  日期：2009.6

  New 1,2-disubstituted ferrocenyl stibines viz. containing -CH2NR or -CH2NHR pendant arm at the ortho-position have been synthesized and characterized by various physicochemical methods. These new ferrocenylstibines were prepared by the nucleophilic substitution reaction of diphenyl[(N,N,N-trimethylaminomethylferrocenyl)iodide]stibine by different primary amines and secondary heterocyclic amines viz. furan-2-ylmethylamine, p-aminoacetophenone, 3-(1-hydroxyethyl)-aniline, 4-hydroxypiperidine, 1-ethylpiperazine and 4-(4-bromophenyl)-4-hydroxypiperidine. Molecular structure of stibine (2), (3), (5) and (7) have been determined by X-ray crystallography. Stibine (2), (5) and (7) show a weak hypervalent Sb-N interaction while stibine (3) does not show this interaction in solid state. (c) 2009 Elsevier B.V. All rights reserved.