trans(Cl)-[Ru(4,4'-bis(carboxyethyl)-2,2'-bipyridine)(CO)2Cl2] | 169832-42-2

• 英文名称: trans(Cl)-[Ru(4,4'-bis(carboxyethyl)-2,2'-bipyridine)(CO)2Cl2]
• CAS: 169832-42-2
• 化学式: C₁₈H₁₆Cl₂N₂O₆Ru
• 分子量: 528.311
• InChiKey: VORMFINRLIJUSH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans(Cl)-[Ru(4,4'-bis(carboxyethyl)-2,2'-bipyridine)(CO)2Cl2] 、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以26%的产率得到cis,cis-[Ru(4,4'-bis(carboxyethyl)-2,2'-bipyridine)(CO)2(CF3SO3)2]
  参考文献：
  名称：

  Designed Synthesis of Mononuclear Tris(heteroleptic) Ruthenium Complexes Containing Bidentate Polypyridyl Ligands

  摘要：

  A general synthetic methodology is reported for tris(bidentate)ruthenium(II) complexes containing three different polypyridyl ligands, based on the sequential addition of the ligands to the oligomer [Ru(CO)(2)Cl-2](n). The tris(heteroleptic) complexes were characterized by FAB mass spectrometry and NMR spectroscopy. An X-ray crystal structure determination was made for the complex, [Ru(Me(2)bpy)(phen)(bpa)](PF6)(2) . C6H14 [C40H43F12N7P2Ru, M = 1062.8; Me(2)bpy = 4,4'-dimethyl-2,2'-bipyridine, phen = 1,10-phenanthroline, bpa = bis(2-pyridyl)amine]: triclinic, space group , a = 14.57(3) Angstrom, b = 13.50(3) Angstrom, c = 12.73(3) Angstrom, alpha = 68.6(2)degrees, beta = 63.5(1)degrees, gamma = 79.8(2)degrees, V = 2082 Angstrom(3), Z = 2. Aspects of the electrochemistry, spectroscopy, and photophysics of the tris(heteroleptic) species are discussed.

  DOI：

  10.1021/ic00128a028
• 作为产物：
  描述：

  dicarbonyldichlororuthenium 、 2,2’-联吡啶-4,4’-二甲酸乙酯 以 甲醇 为溶剂， 以78%的产率得到trans(Cl)-[Ru(4,4'-bis(carboxyethyl)-2,2'-bipyridine)(CO)2Cl2]
  参考文献：
  名称：

  Designed Synthesis of Mononuclear Tris(heteroleptic) Ruthenium Complexes Containing Bidentate Polypyridyl Ligands

  摘要：

  A general synthetic methodology is reported for tris(bidentate)ruthenium(II) complexes containing three different polypyridyl ligands, based on the sequential addition of the ligands to the oligomer [Ru(CO)(2)Cl-2](n). The tris(heteroleptic) complexes were characterized by FAB mass spectrometry and NMR spectroscopy. An X-ray crystal structure determination was made for the complex, [Ru(Me(2)bpy)(phen)(bpa)](PF6)(2) . C6H14 [C40H43F12N7P2Ru, M = 1062.8; Me(2)bpy = 4,4'-dimethyl-2,2'-bipyridine, phen = 1,10-phenanthroline, bpa = bis(2-pyridyl)amine]: triclinic, space group , a = 14.57(3) Angstrom, b = 13.50(3) Angstrom, c = 12.73(3) Angstrom, alpha = 68.6(2)degrees, beta = 63.5(1)degrees, gamma = 79.8(2)degrees, V = 2082 Angstrom(3), Z = 2. Aspects of the electrochemistry, spectroscopy, and photophysics of the tris(heteroleptic) species are discussed.

  DOI：

  10.1021/ic00128a028