| 1219814-33-1

• CAS: 1219814-33-1
• 化学式: C₄₄H₂₈CuN₈*F₆P
• 分子量: 877.27
• InChiKey: CKUKGADVBPMHGC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrakis(actonitrile)copper(I) hexafluorophosphate 、 2,9-Dipyridin-4-yl-1,10-phenanthroline 以 CH₂Cl₂ 、 acetonitrile 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Coordination Chemistry-Assembled Porphyrinic Catenanes

  摘要：

  Non covalent [2]catenanes were synthesized in high yield as kinetic products or as thermodynamic products after completion of an equilibrium. These sophisticated architectures were assembled in two steps, from an oblique bis-zinc(II) porphyrin and two different dipyridyl chelates, by using Cu(I)-N interactions to assemble acyclic complexes and Zn(II)-N interactions to generate rings. H-1 NMR including 2D COSY and ROESY experiments were used to characterize each compound. Spectrophotometric titrations highlight the influence of geometry in terms of distances and angles in non covalent coordinated assemblies. In fact, it was proved that a perfect fit leads to highly stable coordination chemistry-assembled species.

  DOI：

  10.1021/ja910747h