cis-[Pt(1,1’-bis(diphenylphosphino)ferrocene)(trifluoromethanesulfonate)2] | 197642-42-5

• 英文名称: cis-[Pt(1,1’-bis(diphenylphosphino)ferrocene)(trifluoromethanesulfonate)2]
• 英文别名: cis-(1,1'-bis(diphenylphosphino)ferrocene)bis(trifluoromethansulfonato)platinum(II)；cis-[Pt(1,1’-bis(diphenylphosphino)ferrocene)(trifluoromethanesulfonate)₂]；cis-[Pt(dppf)(OTf)₂]；[Pt(dppf)(OTf)₂]；cis-Pt[(1,1'-bis(diphenylphosphino)ferrocene)(trifluoromethanesulfonato)2]；cis-(1,1'-bis(diphenylphosphino)ferrocene)Pt(trifluoromethanesulfonate)2；cis-Pt(1,1'-bis(diphenylphosphino)ferrocene)(trifluoromethanesulfonate)2
• CAS: 197642-42-5
• 化学式: C₃₆H₂₈F₆FeO₆P₂PtS₂
• 分子量: 1047.61
• InChiKey: YPBFEOSUYLTFOA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-[Pt(1,1’-bis(diphenylphosphino)ferrocene)(trifluoromethanesulfonate)2] 、 bis<4-(4'-pyridyl)phenyl>iodonium triflate 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Fast Atom Bombardment Mass Spectrometry for Characterizing Cationic Chelated Species

  摘要：

  DOI：

  10.1002/anie.199625241

文献信息

• Synthesis and characterisation of heterometallic molecular triangles using ambidentate linker: self-selection of a single linkage isomer
  作者：Arun Kumar Bar、Rajesh Chakrabarty、Ki-Whan Chi、Stuart R. Batten、Partha Sarathi Mukherjee

  DOI：10.1039/b900118b

  日期：——

  The coordination driven self-assembly of discrete molecular triangles from a non-symmetric ambidentate linker 5-pyrimidinecarboxylate (5-pmc) and Pd(II)/Pt(II) based 90° acceptors is presented. Despite the possibility of formation of a mixture of isomeric macrocycles (linkage isomers) due to different connectivity of the ambidentate linker, formation of a single and symmetrical linkage isomer in both

  协调驱动 自组装给出了来自非对称环糊精连接基5-嘧啶羧酸盐（5-pmc）和基于Pd（II）/ Pt（II）的90°受体的离散分子三角形的结构。尽管由于环境性连接基的不同连接性而可能形成异构大环化合物（连接异构体）的混合物，但在两种情况下均形成单一对称的连接异构体是一个有趣的发现。而且，据报道大环代表桥接5-pmc的离散金属环的第一个例子。尽管两种情况下溶液成分都是多核的核磁共振 学习和 电喷雾电离质谱 （电喷雾质谱），通过X射线单晶结构分析确定固态组件的身份。 变温NMR 研究清楚地排除了其他因素的形成 大环 乘[4 + 4]或[2 + 2] 自组装 反应成分。
• Self-assembled molecular squares containing metal-based donor: synthesis and application in the sensing of nitro-aromatics
  作者：Vaishali Vajpayee、Hyunuk Kim、Anurag Mishra、Partha Sarathi Mukherjee、Peter J. Stang、Min Hyung Lee、Hwan Kyu Kim、Ki-Whan Chi

  DOI：10.1039/c0dt01481h

  日期：——

  Self-assemblies between a linear Pt-based donor and ferrocene- chelated metallic acceptors produced novel heterometallic squares 4 and 5, which show fluorescence quenching upon the addition of nitro-aromatics.

  线性铂基供体和二茂铁螯合金属受体之间的自组装产生了新型异金属四方体和五方体，在加入硝基芳烃后显示出荧光淬灭现象。
• Self-Assembled Supramolecular Hetero-Bimetallacycles for Anticancer Potency by Intracellular Release
  作者：Anurag Mishra、Seung Chang Lee、Neha Kaushik、Timothy R. Cook、Eun Ha Choi、Nagendra Kumar Kaushik、Peter J. Stang、Ki-Whan Chi

  DOI：10.1002/chem.201403372

  日期：2014.10.27

  Two new tetracationic hetero‐bimetallacycles, compounds 4 and 5, have been constructed from an N,N′‐bis(4‐(pyridin‐4‐ylethynyl)phenyl)pyridine‐2,6‐dicarboxamide ligand (1), and cis‐blocked complexes [M(dppf)(OTf)2] (dppf=1,1′‐bis(diphenylphosphino)ferrocene; OTf=trifluoromethanesulfonate; M=Pd (2), Pt (3)) in CH3NO2/CH2Cl2 (1:1) solvent. Both complexes were isolated with adequate yields as triflate

  两种新的四阳离子杂双金属环化合物4和5由N , N '-双(4-(吡啶-4-基乙炔基)苯基)吡啶-2,6-二甲酰胺配体 ( 1 )和顺式- CH 3 NO 2 /CH 2 中的封闭复合物[M(dppf)(OTf) 2 ] (dppf=1,1'-双(二苯基膦)二茂铁；OTf=三氟甲磺酸盐；M=Pd ( 2 ), Pt ( 3 )) Cl 2 (1:1) 溶剂。两种复合物均以足够产率的三氟甲磺酸盐形式分离，然后使用1 H、13 C 和31 P NMR 光谱、元素分析、UV/Vis 光谱和高分辨率电喷雾质谱 (HR-ESMS)。4的分子结构是通过分子力学力场计算确定的。分析了两种新复合物对 T98G（脑肿瘤）、KB（头颈癌）、SNU-80（甲状腺癌）和 HEK-293 非恶性细胞系的细胞毒性作用。发现复合物4和5的细胞毒性比参考药物顺铂对癌细胞更有效。Annexin-V/PI 染色、caspase-3/7
• Synthesis, Structure, and Heavy Atom Effect of <scp>Pt‐Ferrocene BODIPY</scp> Complexes
  作者：Gajendra Gupta、Junseong Lee、Chang Yeon Lee

  DOI：10.1002/bkcs.12052

  日期：2020.6

  New halogen substituted BODIPY‐based platinum metal complexes were synthesized and their photophysical properties were studied.

  合成了新的卤素取代的BODIPY基铂金属配合物，并研究了其光物理性质。
• Anticancer activity of Pt-selenolate metallacycles
  作者：M. K. Pal、A. G. Majumdar、K. V. Vivekananda、A. P. Wadawale、M. Subramanian、N. Bhuvanesh、S. Dey

  DOI：10.1039/d2nj03931a

  日期：——

  dimers [Pt(P∩P)(4-Sepy)]2(OTf)2 (P∩P = dppe and dppf) and tetramers [Pt(dppf)(4-Epy)]4(OTf)4 showed cis-N,E,(P∩P) coordination around Pt. Stability tests using NMR showed that the oligomers were stable in cell culture medium for at least 24 h. Antiproliferative activity was tested for the new Pt complexes along with each of the two previously reported mononuclear and tetranuclear Pd analogues, and the

  从4 _ _ _ _ _ _ _ _ _ -pyridylthiolate/selenolate 和螯合膦 dppe (diphenylphOSphinoethane) 和 dppf (diphenylphOSphinoferrocene) 或来自中性络合物 [(P ∩ P)Pt(4-Epy) 2 ]。1 H和31 P NMR光谱显示二聚体和四聚体之间缓慢平衡，ESI质谱表明存在金属环的二聚体、三聚体、四聚体和五聚体。二聚体的单晶X射线结构[Pt( P∩P )(4-Sepy)] 2 (OTf)2 (P ∩ P = dppe 和 dppf) 和四聚体 [Pt(dppf)(4-Epy)] 4 (OTf) 4显示围绕 Pt 的顺式-N,E,(P ∩ P) 配位。使用 NMR 的稳定性测试表明，低聚物在细胞培养基中稳定至少 24 小时。使用 MCF7、A549 和 U2OS 癌细胞系测试了新 Pt