trans-[PdCl2(2,4,6-trifluoroaniline)2] | 919990-64-0

• 英文名称: trans-[PdCl2(2,4,6-trifluoroaniline)2]
• 英文别名: trans-[PdCl2(NH2C6H2-2,4,6-F3)2]
• CAS: 919990-64-0
• 化学式: C₁₂H₈Cl₂F₆N₂Pd
• 分子量: 471.525
• InChiKey: WMUQAUQTHFRGKZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,4,6-三氟苯胺 、 bis(benzonitrile)palladium(II) chloride 以 乙醇 为溶剂， 以88%的产率得到trans-[PdCl2(2,4,6-trifluoroaniline)2]
  参考文献：
  名称：

  Phosphane-free C–C Heck couplings catalyzed by Pd(II) fluorinated aniline complexes of the type trans-[PdCl2(NH2ArF)2]

  摘要：

  A series of palladium fluoro-aniline complexes of the trans-[PdCl2(NH2ArF)(2)] type were synthesized in good yields by direct reaction of trans-[PdCl2(C6H5CN)] with (ArNH2)-N-F; Ar-F =C6H3-2,3-F-2 (1), C6H3-2,5-F-2 (2), C6H3-3,4-F-2 (3), C(6)H(3)5-F-2 (4), C6H2-2,3,4-F-3 (5), C6H2-2,3,6-F-3 (6), C6H2-2,4,5-F-3 (7), C6H2-2,4,6-F-3 (8), C6F4-H (9), C6F5, (10). The crystal structures of complexes 3, 4 and 5 were determined. Heck coupling reactions were carried out using complexes 1-10 as catalysts in order to examine the effect of the fluorinated anilines in the reaction of bromobenzene and styrene. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.11.020