[CuCl(2,2'-bis(diphenylphosphano)-1,1'-binaphthyl)(pyridine-2-thione)] | 1072081-54-9

• 英文名称: [CuCl(2,2'-bis(diphenylphosphano)-1,1'-binaphthyl)(pyridine-2-thione)]
• CAS: 1072081-54-9
• 化学式: C₄₉H₃₇ClCuNP₂S
• 分子量: 832.852
• InChiKey: SDYCRCCGBUOCAN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(l) chloride 、 2-巯基吡啶 、 R-(+)-1,1'-联萘-2,2'-双二苯膦 以 乙醇 、 乙腈 为溶剂， 以58%的产率得到[CuCl(2,2'-bis(diphenylphosphano)-1,1'-binaphthyl)(pyridine-2-thione)]
  参考文献：
  名称：

  Copper(I) halide complexes with 2,2′-bis(diphenylphosphano)-1,1′-binaphthyl (rac-binap) and heterocyclic thiones. Racemic compounds in chiral and achiral crystal space groups

  摘要：

  Reactions of copper(I) halides with racemic 2,2'-bis(diphenylphosphano)-1,1'-binaphthyl (rac-binap) in 1:1 molar ratio afforded mononuclear complexes of the type [CuX(rac-binap)] (X = Cl, Br, I) which, on further treatment with 1 equiv. of pyridine-2-thione (py2SH), pyrimidine-2-thione (pymtH) or 4,6-dimethyl-pyrimidine-2-thione (dmpymtH) gave rise to the formation of mixed-ligand complexes of the formula [CuX(rac-binap)(thione)]. The molecular structures of [CuBr(rac-binap)(py2SH)] center dot 2CH(2)Cl(2), [CuBr(rac-binap)(py2SH)] center dot CH2Cl2 and [CuBr(rac-binap)(dmpymtH)] center dot CH2O2 have been established by single-crystal X-ray diffraction. Each of the complexes features a distorted tetrahedral copper(l) center with the phosphane acting in a chelating fashion. The complexes are strongly luminescent in the solid state at ambient temperature. Unusually, the [CuBr(rac-binap)(py2SH)] center dot 2CH(2)Cl(2) molecules crystallise in a chiral space group with independent S- and R-enantiomers in the asymmetric unit. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.06.017