[C5Me5Ir(Cl)2]2(μ-P,P'-diphenyl-1,4-diphospha-cyclohexane) | 1192801-55-0

• 英文名称: [C5Me5Ir(Cl)2]2(μ-P,P'-diphenyl-1,4-diphospha-cyclohexane)
• CAS: 1192801-55-0
• 化学式: C₃₆H₄₈Cl₄Ir₂P₂
• 分子量: 1068.98
• InChiKey: JXSNZYVDWLJMAQ-CCAURHDSSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 、 P,P'-diphenyl-1,4-diphospha-cyclohexane 以 二氯甲烷 为溶剂， 以52%的产率得到[C5Me5Ir(Cl)2]2(μ-P,P'-diphenyl-1,4-diphospha-cyclohexane)
  参考文献：
  名称：

  Group 9 half-sandwich complexes containing the unique P,P′-diphenyl-1,4-diphospha-cyclohexane ligand: Synthesis, X-ray structure analyses and spectroscopic studies

  摘要：

  We wish to report the synthesis and characterization of Group 9 metal complexes with the novel P,P'-diphenyl-1,4-diphospha-cyclohexane (dpdpc) ligand. The complexes are readily prepared by direct ligand substitution reactions from the dichloro-bridged binuclear complexes, [{eta(5)-Cp*M(Cl)(2)}(2)]. The complexes include: [eta(5)-Cp*Rh(Cl)(2)](2)(mu-dpdpc) (1), [eta(5)-Cp*Ir(Cl)(2)](2)(mu-dpdpc) (2), and [eta(5)-Cp*Rh(Cl)(dpdpc)]PF6 (3). The structures for all three complexes are supported by H-1, C-13{H-1}, and P-31{H-1} NMR spectroscopy as well as elemental analysis. The molecular structures of 1 and 3 have also been established by single-crystal X-ray analysis. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.06.023