(1-aminopropane)(1,2,3,4,5-pentamethylcyclopentadienyl)dicarbonyliron(II) tetrafluoroborate | 1361060-40-3

• 英文名称: (1-aminopropane)(1,2,3,4,5-pentamethylcyclopentadienyl)dicarbonyliron(II) tetrafluoroborate
• CAS: 1361060-40-3
• 化学式: BF₄*C₁₅H₂₄FeNO₂
• 分子量: 393.013
• InChiKey: VDJFUUSLXANYLF-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  正丙胺 、 (1,2,3,4,5-pentamethylcyclopentadienyl)(tetrahydrofuran)dicarbonyliron(II) tetrafluoroborate 以 二氯甲烷 为溶剂， 以27%的产率得到(1-aminopropane)(1,2,3,4,5-pentamethylcyclopentadienyl)dicarbonyliron(II) tetrafluoroborate
  参考文献：
  名称：

  Synthesis, characterization and structural elucidation of water-soluble 1-aminoalkane and α,ω-diaminoalkane complexes of the pentamethylcyclopentadienyliron dicarbonyl cation, [Cp∗(CO)2Fe]+

  摘要：

  A series of water-soluble alkylaminopentamethylcyclopentadienyliron dicarbonyl complexes, [Cp*(CO)(2)Fe{NH2(CH2)(n)CH3}]BF4 (n = 2-6; Cp* = eta(5)-C5Me5) and the diaminopropane bridged complex, [{Cp*(CO)(2)Fe}(2){mu-NH2(CH2)(3)NH2}](BF4)(2) have been synthesized and fully characterized. [Cp* (CO)(2)Fe{NH2(CH2)(5)CH3}]BF4 undergoes counteranion exchange with sodium tetraphenylborate in both aqueous and organic media to give water insoluble [Cp* (CO)(2)Fe{NH2(CH2)(5)CH3}]BPh4. The molecular structures for compounds [Cp*(CO)(2)Fe{NH2(CH2)(3)CH3}]BF4 and [{Cp*(CO)(2)Fe}(2){mu-NH2(CH2)(3)NH2}](BF4)(2) have been determined by single crystal X-ray crystallography and show that they crystallize in the orthorhombic and monoclinic crystal systems, respectively. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.09.058