bis(triphenyl-λ5-phosphanylidene)azanium;tribromogold;bromide | 201612-46-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(triphenyl-λ5-phosphanylidene)azanium;tribromogold;bromide
• CAS: 201612-46-6
• 化学式: AuBr₄*C₃₆H₃₀NP₂
• 分子量: 1055.17
• InChiKey: GMPFHRFWRFTYCI-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(triphenyl-λ5-phosphanylidene)azanium;tribromogold;bromide 、 4,5-bis(benzoylthio)-1,3-dithiole-2-selenone 在 sodium 作用下， 以 甲醇 为溶剂， 以90%的产率得到bis(triphenyl-λ5-phosphanylidene)azanium;gold(3+);2-selanylidene-1,3-dithiole-4,5-dithiolate
  参考文献：
  名称：

  Gold complexes with 2-selenoxo-1,3-dithiole-4,5-dithiolato

  摘要：

  The reaction of Na(2)dmise (dmise = 2-selenoxo-1,3-dithioIe-4,5-dithielate) with [AuClL] in 1:2 molar ratio affords [Au-2(dmise)L-2] (L = PR3 or CH2PPh3) but in 1:1 ratio in the presence of (NBu4) Pr gives (NBu4)[Au(dmise)L]. The PPh2Me dinuclear derivative further reacts with [Au(OClO3)(PPh2Me)] to give [Au-3(dmise)(PPh2Me3)(3)]ClO4. The reaction with [Au-2(P-P)Cl-2] renders [Au-2(P-P)(dmise)](n) with different nuclearity depending on the diphosphine used (P-P = dppe, n = 1; dppm, n = 2). Anionic derivatives (PPN)(2)[Au-2(dmise)(C6F5)(2)] and (PPN)[Au(dmise)(2)] are obtained by reaction with the corresponding haloanionic gold complexes. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00302-1