| 949152-86-7

• CAS: 949152-86-7
• 化学式: C₄₅H₃₇ClNO₃P₂Re
• 分子量: 923.401
• InChiKey: BLVGRSJSVDNPPZ-QSMANLJDSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [ReOCl₃(PPh₃)₂] 、 N-salicylideneglycine 、 三苯基膦 以 乙醇 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Synthesis and structural characterisation of new Re(III) complexes using aldimines of α-amino acids as coligands

  摘要：

  Complexes of the general formula [Re-III(L)CI(PPh3)2] have been synthesised by reacting H2L and [ReOCl3(PPh3)(2)] in ethanol. Here H2L represents imines of alpha-amino acids (glycine, L-alanine, L-valine, L-phenylalanine) derived from salicylaldehyde and naphthaldehyde. The crystal structure of one complex has been determined. The complexes are monomiclear, paramagnetic and display paramagnetic H-1 NMR in CDCl3 solution. Their spectral and redox properties are scrutinised. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.03.036