dichloro[pentaphenoxy(2-pyridylmethoxy)cyclotriphosphazene]platinum(II) | 1124368-83-7

• 英文名称: dichloro[pentaphenoxy(2-pyridylmethoxy)cyclotriphosphazene]platinum(II)
• CAS: 1124368-83-7；924278-12-6
• 化学式: C₃₆H₃₁Cl₂N₄O₆P₃Pt
• 分子量: 974.573
• InChiKey: UXAOYWIQZLAQOO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cis-dichlorobis(propiononitrile)platinum(II) 、 pentaphenoxy(2-pyridylmethoxy)cyclotriphosphazene 以 氯仿 为溶剂， 以18.5%的产率得到dichloro[pentaphenoxy(2-pyridylmethoxy)cyclotriphosphazene]platinum(II)
  参考文献：
  名称：

  Synthesis and molecular structure of platinum(II) complexes with cyclotriphosphazenes containing pyridylalkylamino and pyridylmethoxy groups

  摘要：

  The interaction of platinum(II) nitrile complexes with polydentate ligands, pentaphenoxy(2-pyridylmethylamino) cyclotriphosphazene (L-1), pentaphenoxy( 3-pyridylmethylamino) cyclotriphosphazene (L-2), pentaphenoxy[2-(2- pyridyl) ethylamino] cyclotriphosphazene (L-3), and pentaphenoxy(2-pyridylmethoxy)cyclotriphosphazene (L-4), was studied. The synthesized complexes were characterized by single-crystal X-ray diffraction, H-1 and P-31 NMR spectroscopy, IR spectroscopy, FAB mass spectrometry, and other methods. In complexation of phosphazenes L-1 L-3 with Pt(II) ions, nitrogen atoms of the pyridine ring and alkylamine fragment participate in the coordination to form chelate rings. In the complex with L-4, the substituted phosphazene is coordinated via nitrogen atoms of the pyridyl group and cyclotriphosphazene ring to form a seven-membered ring.

  DOI：

  10.1134/s1070363207110059