| 1127647-98-6

• CAS: 1127647-98-6
• 化学式: C₇₂H₄₈CaEu₂N₈O₈
• 分子量: 1497.22
• InChiKey: NUABNFPHEXJLAD-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris(quinolin-8-olato)europium(III) 、 calcium(II) 8-quinolinolate 在 1,2,4,5-tetramethylbenzene 作用下， 以 neat (no solvent) 为溶剂， 以15%的产率得到
  参考文献：
  名称：

  Novel rare earth quinolinolate complexes

  摘要：

  The reaction of curopium 8-quinolinolate Eu(OQ)(3) with calcium 8-quinolinolate, Ca(OQ)(2), in the flux 1,2,4,5-tetramethylbenzene (TMB) at 210 degrees C yields thebimetallic [Eu2Ca(OQ)(8)], which is a linear tri-nuclear complex with two eight coordinate europium atoms flanking a six coordinate calcium atom bonded by six bridging phenolate oxygen atoms. A similar reaction between La(OQ)(3) and CO(OQ)(2) gave [LaCO2(OQ)(7)], in which two six coordinate cobalt atoms flank an eight coordinate lanthanum atom with six bridging phenolate oxygen atoms and a terminal OQ group. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2007.04.253