| 689219-70-3

• CAS: 689219-70-3
• 化学式: BF₄*C₁₆H₂₉O₁₀Rh₂S₂
• 分子量: 738.148
• InChiKey: QRMCRTCCDIKHKT-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (甲硫基)乙酸乙酯 以 二氯甲烷 、 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Cationic Carboxylato Complexes of Dirhodium(II) with Oxo Thioethers:  Promising Catalysts with Unusual Coordination Modes

  摘要：

  Removal of an acetato ligand from dirhodium(II) acetato complexes with thioethers of the general structure [Rh-2(mu-OAc)(4)(RSCH(2)Z)(2)] yields the cationic complexes [Rh-2(mu-OAc)(3)(RSCH(2)Z)(2)](BF4) (R = Me, Ph; Z = C(O)OEt, CH2(O)OMe). The methylthio complex with Z = C(O)OEt has been structurally characterized and found to exhibit an unusual bidentate O-S coordination of the oxo thioether ligands. Preliminary tests indicate that the complex is a promising catalyst of the silylformylation or hydrosilylation of 1-hexyne with dimethylphenylsilane.

  DOI：

  10.1021/om0342560