[Fe2{μ-CN(Me)2}(μ-H)(CO)(CO)(Cp)2] | 306741-80-0

• 英文名称: [Fe2{μ-CN(Me)2}(μ-H)(CO)(CO)(Cp)2]
• 英文别名: [Fe₂{μ-CN(Me)₂}(μ-H)(CO)(CO)(Cp)₂]；[Fe2(μ-CNMe2)(μ-H)(CO)2(Cp)2]
• CAS: 306741-80-0
• 化学式: C₁₅H₁₇Fe₂NO₂
• 分子量: 354.999
• InChiKey: FKQWTFINZNXIHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Fe2(η(5)-C5H5)2(CO)(MeCN)(μ-CO)(μ-CNMe2)]CF3SO3 、 sodium tetrahydroborate 以 乙腈 为溶剂， 以64%的产率得到[Fe2{μ-CN(Me)2}(μ-H)(CO)(CO)(Cp)2]
  参考文献：
  名称：

  Reactions of acetonitrile di-iron μ-aminocarbyne complexes; synthesis and structure of [Fe2(μ-CNMe2)(μ-H)(CO)2(Cp)2]

  摘要：

  The complexes [Fe-2{mu-CN(Me)R}(mu-CO)(NCMe)(CO)(Cp)(2)]SO3CF3 (R = Me, 2a; 2,6-Me2C6H3, 2b' CH2Ph 2c), easily obtained from the corresponding [Fe-2{mu-CN(Me)R}(mu-CO)(CO)(2)(Cp)(2)]SO3CF3 (1a-c) precursors, react with NBu4CN affording the cyano complexes [Fe-2{mu-CN(Me)R}(mu-CO)(CN)(CO)(Cp)(2)] (3a-c) by displacement of the MeCN ligand. The analogous reaction with NBu4Cl leads to the formation of [Fe-2{mu-CN(Me)R}(mu-CO)(Cl)(CO)(Cp)(2)] (4a-b). The mu-hydride complexes [Fe-2{mu-CN(Me)R}(mu-H)(CO)(2)(Cp)(2)] (5a-b) have been prepared by reaction of 1a-b with NaBH4. The corresponding diruthenium compound [Ru-2(mu-CNMe2)(mu-H)(CO)(2)(Cp)(2)] (6) has been similarly obtained from [Ru-2(mu-CNMe2)(mu-CO)(NCMe) (CO)(Cp)(2)]SO3CF3. The X-ray molecular structure of 5a is that expected for cis isomers of this family of compounds. It shows a chiral conformation of the C5H5 ligands and the crystals are a conglomerate of enantiomeric individuals. NMR spectra of the various compounds, which are indicative of the presence of alpha-beta or cis-trans isomeric mixtures, are reported and discussed. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00337-5

文献信息

• Diiron-aminocarbyne complexes with amine or imine ligands: C–N coupling between imine and aminocarbyne ligands promoted by tolylacetylide addition to [Fe2{μ-CN(Me)R}(μ-CO)(CO)(NHCPh2)(Cp)2][SO3CF3]
  作者：Luigi Busetto、Fabio Marchetti、Stefano Zacchini、Valerio Zanotti、Eleonora Zoli

  DOI：10.1016/j.jorganchem.2004.09.043

  日期：2005.1

  A terminally coordinated CO ligand in the complexes [Fe2μ-CN(Me)R}(μ-CO)(CO)2(Cp)2][SO3CF3] (R = Me, 1a; R = Xyl, 1b; Xyl = 2,6-Me2C6H3), is readily displaced by primary and secondary amines (L), in the presence of Me3NO, affording the complexes [Fe2μ-CN(Me)R}(μ-CO)(CO)(L)(Cp)2][SO3CF3] (R = Me, L = NH2Et, 4a; R = Xyl, L = NH2Et, 4b; R = Me, L = NH2Pri, 5a; R = Xyl, L = NH2Pri, 5b; R = Xyl, L = NH2C6H11

  [Fe 2 μ-CN（Me）R}（μ-CO）（CO）2（Cp）2 ] [SO 3 CF 3 ]（R = Me，1a ; R = Xyl ，1b ; Xyl = 2,6-Me 2 C 6 H 3），在存在Me 3 NO的情况下很容易被伯胺和仲胺（L）取代，得到络合物[Fe 2 μ-CN（Me） R}（μ-CO）（CO）（L）（Cp）2 ] [SO 3 CF 3 ]（R = Me，L = NH 2 Et，4a ; R = Xyl，L = NH 2 Et，4b ; R =我，L = NH2 Pr i，5a ; R = Xyl，L = NH 2 Pr i，5b ; R =的Xyl，L = NH 2 C ^ 6 ħ 11，6 ; R = Xyl，L = NH 2 Ph，7；R =的Xyl，L = NH 3，8 ; R = Me中，L = NHMe 2，图9A ; R =的Xyl，L = NHMe