[Ru(pyrazole)3(μ-pyrazolate)3Co((3-isopropyl-4-bromopyrazolate)3BH-κ3N)] | 1310069-69-2

• 英文名称: [Ru(pyrazole)3(μ-pyrazolate)3Co((3-isopropyl-4-bromopyrazolate)3BH-κ3N)]
• CAS: 1310069-69-2
• 化学式: C₃₆H₄₆BBr₃CoN₁₈Ru
• 分子量: 1141.47
• InChiKey: JKRJJSPLYMVAEO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  CoCl((3-isopropyl-4-bromopyrazolate)3BH-κ3N) 、 Ru(pyrazolate)2(pyrazole)4 在 N(CH₂CH₃)3 作用下， 以 二氯甲烷 为溶剂， 以71%的产率得到[Ru(pyrazole)3(μ-pyrazolate)3Co((3-isopropyl-4-bromopyrazolate)3BH-κ3N)]
  参考文献：
  名称：

  Use of pyrazolyl ligands for the formation of a bimetallic cobalt–ruthenium complex

  摘要：

  A straightforward route to Ru(pyz)(2)(Hpyz)(4) (Hpyz = pyrazole) has been developed. This has been found to react readily with a modified Co(pyrazolylborate)Cl complex in the presence of triethylamine as an HCl acceptor to yield a bimetallic cobalt-ruthenium complex, in which the two metals are each six-coordinate, and bridged by three pyrazolyl anions. Both species have been characterized structurally, as has a modified Co(pyrazolylborate)(2) complex. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.04.023