| 178383-87-4

• CAS: 178383-87-4
• 化学式: AlCl₄*C₃₉H₃₈ClMoP₃
• 分子量: 899.839
• InChiKey: XJIKYBAAZPRYTB-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三氯化铝 、 {Mo(η5-C5H5)Cl2}(n) 、 双(2-二苯基膦乙基)苯基磷 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Four-legged piano stool molybdenum(II) compounds without carbonyl ligands—3 cyclopentadienyl and indenyl complexes containing the tridentate ligand Ph2PCH2CH2P(Ph)CH2CH2PPh2(triphos) via reduction of molybdenum(III) precursors

  摘要：

  The carbonyl-free, half-sandwich molybdenum(II) complexes CpMoCl(triphos) (1) and IndMoX(triphos) [X = Cl (2); I (3); triphos = Ph(2)PCH(2)CH(2)P(Ph)CH(2)CH(2)PPh(2); Ind = eta(5)-C7H9 or indenyl] have been synthesized by either reduction of CpMoCl(2) in the presence of triphos or by reduction and transmetallation of MoX(3)(triphos) (X = Cl, I) with CpNa or IndNa. The spectroscopic properties indicate a saturated, 18-electron structure in each case. All compounds are susceptible to oxidation in chlorinated hydrocarbons and the oxidation of 1 has been studied in detail both chemically and electrochemically. Compound [1](PF6-)-P-+ has been obtained by oxidation of 1 with AgPF6, whereas the corresponding AlCl4- salt has been prepared in a one-pot reaction from CpMoCl(2), triphos and AlCl3. The structure of 1 has been confirmed by X-ray crystallography as a four-legged piano stool with an eta(5)-cyclopentadienyl ring and a tridentate triphos ligand. Copyright (C) 1996 Elsevier Science Ltd.

  DOI：

  10.1016/0277-5387(95)00517-x