Ru(CCCCAg)(dppe)(η5-C5Me5) | 1234178-82-5

• 英文名称: Ru(CCCCAg)(dppe)(η5-C5Me5)
• 英文别名: Ru(CCCCAg)(dppe)Cp*
• CAS: 1234178-82-5
• 化学式: C₄₀H₃₉AgP₂Ru
• 分子量: 790.635
• InChiKey: UBBPDMWMYJDYDN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ru(CCCCAg)(dppe)(η5-C5Me5) 、 [Ag2(μ-dppm)2(MeCN)2](ClO4)2 以 甲醇 、 二氯甲烷 为溶剂， 以76%的产率得到[Ag6(CCCC[Ru(dppe)(η5-C5Me5)])4(dppm)2](ClO4)2*9MeCN
  参考文献：
  名称：

  Preparation and molecular structures of the decanuclear diynyl-ruthenium-silver and -copper complexes [M6{μ3-CCCC[Ru(dppe)Cp∗]}4(μ-dppm)2](BF4)2 (M=Ag, Cu)

  摘要：

  Reactions between [M-2(dppm)(2)(NCMe)(2)]X-2 [M = Ag, X = ClO4; M = Cu, X = BF4] and Ru(C CC CM)(dp-pe)Cp* [M = Ag, Cu; generated in situ from Ru(C CC CH)(dppe)Cp* and AgNO3 or CuCl(PPh3), respectively] afford the cationic mixed-metal cluster diynyl complexes [M-6{mu(3)-C CC C[Ru(dppe)Cp*]}(4)(mu-dppm)(2)]X-2, of which the structures were determined by single-crystal XRD studies. Electrochemical studies indicate that there is no interaction between the ruthenium centres. Reactions between [M-2(mu-dppm)(2)(NCMe)(2)](BF4)(2) and Ru(C CC CM')(dppe)Cp* (M,M' = Cu, Ag) afforded a mixture of Ag-6 Cu-n(n) clusters, as shown by ES-MS and crystallographic studies. Preliminary studies suggest that extensive dis-proportionation occurs in solution. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.03.016
• 作为产物：
  描述：

  Ru(C≡CC≡CH)(dppe)Cp* 、 silver nitrate 在 1,8-diazabicyclo[5.4.0]undec-7-ene 作用下， 以 乙腈 为溶剂， 以75%的产率得到Ru(CCCCAg)(dppe)(η5-C5Me5)
  参考文献：
  名称：

  Preparation and molecular structures of the decanuclear diynyl-ruthenium-silver and -copper complexes [M6{μ3-CCCC[Ru(dppe)Cp∗]}4(μ-dppm)2](BF4)2 (M=Ag, Cu)

  摘要：

  Reactions between [M-2(dppm)(2)(NCMe)(2)]X-2 [M = Ag, X = ClO4; M = Cu, X = BF4] and Ru(C CC CM)(dp-pe)Cp* [M = Ag, Cu; generated in situ from Ru(C CC CH)(dppe)Cp* and AgNO3 or CuCl(PPh3), respectively] afford the cationic mixed-metal cluster diynyl complexes [M-6{mu(3)-C CC C[Ru(dppe)Cp*]}(4)(mu-dppm)(2)]X-2, of which the structures were determined by single-crystal XRD studies. Electrochemical studies indicate that there is no interaction between the ruthenium centres. Reactions between [M-2(mu-dppm)(2)(NCMe)(2)](BF4)(2) and Ru(C CC CM')(dppe)Cp* (M,M' = Cu, Ag) afforded a mixture of Ag-6 Cu-n(n) clusters, as shown by ES-MS and crystallographic studies. Preliminary studies suggest that extensive dis-proportionation occurs in solution. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.03.016