| 1112908-10-7

• CAS: 1112908-10-7
• 化学式: C₃₆H₃₀Cl₃N₃P₂Ti
• 分子量: 720.841
• InChiKey: PZRRNQXFIOAHNO-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  四氯化钛 、 [[[[Diphenyl(phenylimino)-lambda5-phosphanyl]amino]-diphenyl-lambda5-phosphanylidene]amino]benzene 在 三乙胺 作用下， 以 甲苯 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Cyclometallaphosphazene Complexes of Titanium(IV)

  摘要：

  Cyclometallacyclophosphazene complexes of titanium(IV) corresponding to [{N(PPh2NR)(2)}(n)TiCl4-n], [{N(PPh2NR)(2)}(n)TiCl2-n] (OPri)(2)], [{N(PPh2NR)(2)}(n)[GRAPHICS](OPri)(2-n)](R = Ph or SiMe3, G = CH2CH2, n = 1 or 2) have been synthesized under anhydrous and inert conditions by the reaction of acyclic bis-silylated phosphazene ligand (A), [HN(PPh2NSiMe3)(2)] with TiCl4, TiCl2(OPri)(2) or[GRAPHICS](OPri)(2) in 1:1 and 2:1 molar ratios. These titanatriazadiphosphorines were characterized by elemental analyses (C, H, N, Cl and Ti), molecular weight determination, and spectral studies including IR and NMR (H-1, C-13, and P-31), which have indicated monomeric nature of the complexes and bidentate mode of bonding by phosphazene moiety leading to a trigonal bipyramidal and octahedral geometries around the titanium atom in 5 and 6 coordination numbers.

  DOI：

  10.1080/15533170701674868