(η-C5H3Me2BMe)Fe(η5-C5Me5) | 1122104-01-1

• 英文名称: (η-C5H3Me2BMe)Fe(η5-C5Me5)
• 英文别名: [(η5-Cp*)Fe(η-C5H3Me2BMe)]
• CAS: 1122104-01-1
• 化学式: C₁₈H₂₇BFe
• 分子量: 310.07
• InChiKey: UDNISIZQXKZYTH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  二氯(四甲基环丁二烯)铂(II) 、 (η-C5H3Me2BMe)Fe(η5-C5Me5) 、 silver trifluoromethanesulfonate 以 硝基甲烷 为溶剂， 以17%的产率得到[(η-C4Me4)Pt(μ-η:η-C5H3Me2BMe)Fe(η5-C5Me5)](SO3CF3)2
  参考文献：
  名称：

  Metallacarboranes and triple-decker complexes with the (C4Me4)Pt fragment

  摘要：

  Complex Cb*PtCl2 (Cb*=eta-C4Me4) reacts with the carborane anions [7,8-C2B9H11](2) and [9-SMe2-7,8-C2B9H10] giving platinacarboranes Cb*Pt(eta-7,8-C2B9H11) (1) and [Cb*Pt(eta-9-SMe2-7,8-C2B9H10)](+) (2), respectively. Reactions of the [Cb*Pt](2+) fragment (as a labile nitromethane solvate) with the sandwich compounds Cp*Fe(eta-C5H3Me2BMe) and Cp*Rh(eta(5)-C4H4BPh) afford the triple-decker cations [Cb*Pt(mu-eta:eta-C5H3Me2BMe)FeCp*](2+) (3) and [Cb*Pt(mu-eta(5): eta(5)-C4H4BPh)RhCp*](2+) (4) with bridging boratabenzene and borole ligands. The structures of 1 and 3(CF3SO3)(2) were determined by X-ray diffraction. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.09.029

文献信息

• 1,2,3,4,7-Pentamethylindenyl complex [(η5-C9H2Me5)RhI2]2 as a synthon for the [(η5-C9H2Me5)Rh]2+ fragment
  作者：D. A. Loginov、A. V. Vologzhanina、P. V. Petrovskii、M. M. Vinogradov、A. R. Kudinov

  DOI：10.1007/s11172-008-0215-4

  日期：2008.8

  The reaction of the iodide complex [(η5-C9H2Me5)RhI2]2 (1) or the acetonitrile complex [(η5-C9H2Me5)Rh(MeCN)3]2+ with Tl[Tl(η-7,8-C2B9H11)] afforded rhodacarborane (η5-C9H2Me5)Rh(7,8-C2B9H11) (2). The cationic triple-decker complex with the bridging boratabenzene ligand [Cp*Fe(μ-η:η-C5H3Me2BMe)Rh(η5-C9H2Me5)]2+ (3) was synthesized by the reaction of the nitromethane solvate [(η5-C9H2Me5)Rh(MeNO2)3]2+ with the sandwich compound Cp*Fe(η-C5H3Me2BMe). The structure of 2 was established by X-ray diffraction.

  碘化物络合物[(η5-C9H2Me5)RhI2]2 (1) 或乙腈络合物[(η5-C9H2Me5)Rh(MeCN)3]2+ 与 Tl[Tl(η-7,8-C2B9H11)] 反应生成了罗达硼烷 (η5-C9H2Me5)Rh(7,8-C2B9H11)(2)。通过硝基甲烷溶胶 [(η5-C9H2Me5)Rh(MeNO2)3]2+与夹心化合物 Cp*Fe(η-C5H3Me2BMe) 的反应，合成了具有桥接硼苯配体的阳离子三迭代配合物 [Cp*Fe(μ-η:η-C5H3Me2BMe)Rh(η5-C9H2Me5)]2+（3）。通过 X 射线衍射确定了 2 的结构。