Pt(1-phenyl-isoquinoline)(1-phenyl-isoquinoline(-1H))(Cl) | 866566-10-1

• 英文名称: Pt(1-phenyl-isoquinoline)(1-phenyl-isoquinoline(-1H))(Cl)
• 英文别名: Pt(piq)(Hpiq)(Cl)；[PtCl(1-phenylisoquinoline)(1-phenylisoquinoline(-1H))]
• CAS: 866566-10-1
• 化学式: C₃₀H₂₁ClN₂Pt
• 分子量: 640.043
• InChiKey: YDJGENGCRUCSMJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Pt(1-phenyl-isoquinoline)(1-phenyl-isoquinoline(-1H))(Cl) 、 3-(5-(bicyclo[2.2.1]hept-5-en-2-yl)pentyl)pentane-2,4-dione 在 sodium carbonate 作用下， 以 乙二醇乙醚 为溶剂， 以20%的产率得到platinum(II) (1-phenyl-isoquinolinato-N,C(2'))(3-(5-(bicyclo[2.2.1]hept-5-en-2-yl)pentyl)pentane-2,4-dionato-O,O)
  参考文献：
  名称：

  Synthesis and Characterization of Polymerizable Phosphorescent Platinum(II) Complexes for Solution-Processible Organic Light-Emitting Diodes

  摘要：

  A norbomene-functionalized derivative of acetylacetone has been used to synthesize a series of new polymerizable norbornene-derivatized phosphorescent platinum complexes of the form Pt(C ( ) over capN)(O ( ) over capO*) where CAN represents a cyclometalated ligand and O ( ) over capO* represents the functionalized acetylacetonate ligand. The complexes have been fully characterized, and the structures of three examples have been determined by X-ray diffraction. Solution absorption and luminescence spectra and electrochemical data are very similar to those for analogues without these polymerizable groups. A 9,9-dialkyl-2,7-di(carbazol-9-yl)fluorene material, in which one of the alkyl groups bears a norbornene group, has been synthesized and copolymerized with the Pt(C ( ) over capN)(O ( ) over capO*) Complexes using Grubbs ruthenium catalysts, resulting in copolymers with broad molecular weight distributions. The copolymers have been used as lumophores in organic light-emitting diodes, thus demonstrating that platinum phosphors can be successfully integrated into the "hybrid" approach to organic light-emitting diodes, in which molecules with transport or luminescent properties are covalently attached to electronically inert polymer backbones to give solutionprocessible materials. Emission from aggregate states appears to play a similar role in these copolymers to that seen in vapor-deposited devices based on small phosphor and host molecules; in particular, considerable aggregate emission is observed when a phosphor with blue solution emission is used in the devices.

  DOI：

  10.1021/om700373c
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 1-苯基异喹啉 以 乙二醇乙醚 、 水 为溶剂， 以85.6%的产率得到Pt(1-phenyl-isoquinoline)(1-phenyl-isoquinoline(-1H))(Cl)
  参考文献：
  名称：

  环金属化铂络合物：高产率合成，表征和晶体结构

  摘要：

  K的一锅反应2氯铂酸4和各种2-芳基吡啶，HC ∧ N，在3：2-乙氧基乙醇和1（V / V）混合物H 2 O不连到80℃16次小时，得到环金属铂络合物，Pt（C∧N）（HC∧N）（Cl），高收率。这些已经被充分表征，并且在一种情况下，已经确定了X射线结构。

  DOI：

  10.1016/j.jorganchem.2005.05.042

文献信息

• Organoplatinum(II) Cruciform: A Versatile Building Block to Fabricate 2D Microcrystals with Full‐Color and White Phosphorescence and Anisotropic Photon Transport
  作者：Fa‐Feng Xu、Wei Zeng、Meng‐Jia Sun、Zhong‐Liang Gong、Zhong‐Qiu Li、Yong Sheng Zhao、Jiannian Yao、Yu‐Wu Zhong

  DOI：10.1002/anie.202116603

  日期：2022.3.7

  controllable preparations of two-dimensional phosphorescent crystals remain a challenging task. In stark contrast to the conventional one-dimensional assemblies of square-planar platinum complexes, organoplatinum(II) complexes with a cruciform shape form two-dimensional microcrystals with full-color and white phosphorescence by unique molecular stackings, opening a new avenue for the preparations of phosphorescent

  二维磷光晶体的可控制备仍然是一项具有挑战性的任务。与传统的方形平面铂配合物的一维组装体形成鲜明对比的是，十字形的有机铂（II）配合物通过独特的分子堆积形成具有全彩和白色磷光的二维微晶，为制备开辟了新途径用于先进光子应用的磷光微/纳米结构。
• Highly Phosphorescent Planar Chirality by Bridging Two Square-Planar Platinum(II) Complexes: Chirality Induction and Circularly Polarized Luminescence
  作者：Jintong Song、Hui Xiao、Lizhi Fang、Lang Qu、Xiangge Zhou、Zong-Xiang Xu、Cheng Yang、Haifeng Xiang

  DOI：10.1021/jacs.1c11699

  日期：2022.2.9

  When the achiral ligand 1,3,4-oxadiazole-2-thiol (OXT) was used to bridge two square-planar complexes, a pair of racemic R/S planar-chiral binuclear Pt(II) complexes was obtained, which could be separated by chiral high-performance liquid chromatography (HPLC). Moreover, enantiopure R,R,R or S,S,S complexes could be prepared by the use of chiral (R)-/(S)-binaphthalene-derived OXT ligands in 99% diastereoselectivity

  手性有机金属配合物已显示出许多潜在和实际的应用。然而，为方形平面配合物构建金属诱导的手性仍然是一个巨大的挑战，因为它们的二维平面分子结构通常可以叠加在它们的镜像上。在这里，我们报告了一种通过构建 3D 双层分子结构来实现新型平面手性的简单有效的方法。当使用非手性配体 1,3,4-oxadiazole-2-thiol (OXT) 桥接两个方平面配合物时，得到一对外消旋R / S平面手性双核 Pt(II)配合物，可手性高效液相色谱（HPLC）分离。此外，对映纯R,R,R或S,S,S在不使用手性 HPLC 的情况下，可以通过使用手性 ( R )-/( S )-联萘衍生的 OXT 配体以 99% 的非对映选择性制备配合物。联萘基团有助于确保良好的溶解性和平滑的无定形薄膜形态，但对光物理性质影响不大。所得配合物显示出强烈的橙红色和近红外磷光，量子产率高达 83.4%，可用作高效溶液处理有机发光二极管