4,7-di-tert-butyl-2,2,2-triphenyl-5-((triphenylstannyl)oxy)-2l5-benzo[d][1,3,2]dioxastannole | 152730-54-6

• 英文名称: 4,7-di-tert-butyl-2,2,2-triphenyl-5-((triphenylstannyl)oxy)-2l5-benzo[d][1,3,2]dioxastannole
• CAS: 152730-54-6
• 化学式: C₅₀H₄₉O₃Sn₂
• 分子量: 935.357
• InChiKey: BSBWBZNJEKCJRZ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,5-di-tert-butyl-6-hydroxy-1,4-benzoquinone 在 KOH 作用下， 以 甲醇 、 甲苯 为溶剂， 生成 4,7-di-tert-butyl-2,2,2-triphenyl-5-((triphenylstannyl)oxy)-2l5-benzo[d][1,3,2]dioxastannole
  参考文献：
  名称：

  Synthesis, structure, and properties of 2-(triphenylstannyloxy)-3,6-di-tert butyl-1,4-benzoquinone

  摘要：

  2-(triphenylstannyloxy)-3,6-di-tert-butyl-1,4-benzoquinone (1) was obtained from the potassium salt of 3,6-ditert-butyl-2-hydroxy-1,4-benzoquinone and triphenyltin bromide in methanol and characterized by x-ray diffraction analysis, electronic, IR, and NMR spectroscopy. According to x-ray diffraction data, the single crystal of 1 has the structure of a chain metal polymer with bridging hydroxy-para-quinone ligands; the coordination number of tin is six. Complex 1 is reduced by cobaltocene to the corresponding radical anion. In solutions, 1 reacts with metal-centered radicals SnPh3, PbPh3, and Mn(CO)5 with formation of paramagnetic binuclear ortho-semiquinone complexes.

  DOI：

  10.1007/bf01150751