| 1356825-68-7

• CAS: 1356825-68-7
• 化学式: C₃₇H₅₀AlMnN₂O₂
• 分子量: 636.736
• InChiKey: YLRXNAGUVOSGQO-AXKFIATASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  methylcyclopentadienyl manganese(I) tricarbonyl 、 [(HC(CMeN(2,6-i-Pr2C6H3))2)AlH2] 以 甲苯 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  σ-Alane Complexes of Chromium, Tungsten, and Manganese

  摘要：

  Photolytic ligand displacement and salt metathesis routes have been exploited to give access to kappa(1) sigma-alane complexes featuring Al-H bonds bound to [W(CO)(5)] and [Cp'Mn(CO)(2)] fragments, together with a related kappa(2) complex of [Cr(CO)(4)]. Spectroscopic, crystallographic, and quantum chemical studies are consistent with the alane ligands acting predominantly as sigma-donors, with the resulting binding energies calculated to be marginally greater than those found for related dihydrogen complexes.

  DOI：

  10.1021/ja2119892