Λ,Λ-[Fe(N,N'-disalicylidene-(R)-1,1'-binaphthyl-2,2'-diaminate(2-))2(OMe)2]*Et2O*H2O | 1175516-25-2

• 英文名称: Λ,Λ-[Fe(N,N'-disalicylidene-(R)-1,1'-binaphthyl-2,2'-diaminate(2-))2(OMe)2]*Et2O*H2O
• CAS: 1175516-25-2
• 化学式: C₄H₁₀O*C₇₀H₅₀Fe₂N₄O₆*H₂O
• 分子量: 1247.02
• InChiKey: OMRBHAPKGAVIIT-UQUNPUNXSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 乙醚 、 iron(III) chloride hexahydrate 、 (R)-N,N’-bis(salicylidene)-1,1’-binaphthyl-2,2’-diamine 在 triethylamine 作用下， 以 甲醇 为溶剂， 生成 Λ,Λ-[Fe(N,N'-disalicylidene-(R)-1,1'-binaphthyl-2,2'-diaminate(2-))2(OMe)2]*Et2O*H2O
  参考文献：
  名称：

  Chiral dinuclear complexes with tetradentate ligands derived from (R)-(+)-1, 1′-binaphthyl-2,2′-diamine

  摘要：

  Novel chiral dinuclear complexes of Delta,Delta-[Ni-2(II)((R)-Hsalbn)((R)-salbn)(MeCN)(2)](ClO4) center dot 2MeCN (1) and Delta,Delta-[Fe-2(III)((R)-salbn)(2)(OMe)(2)] center dot Et2O center dot H2O (2) ((R)-H(2)salbn = N,N'-disalicylidene-(R)-1,1'-binaphthyl-2,2'-diaminate) were prepared. X-ray crystal structure analyses revealed that both complexes crystallized in chiral space groups of P2(1)2(1)2(1) and P4(1)2(1)2, respectively. In 1, two Ni(II) ions with Delta configuration are bridged by phenoxo groups of (R)-salbn, while in 2 mu(2)-methoxo ions bridge two Fe(III) ions leading to the Delta absolute configuration. Dc magnetic susceptibility measurements suggested antiferromagnetic interactions operative in 1 and 2. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.11.029