FI(2)-Zr2 | 1005788-73-7

• 英文名称: FI(2)-Zr2
• CAS: 1005788-73-7
• 化学式: C₄₄H₅₆Cl₆N₂O₄Zr₂
• 分子量: 1072.11
• InChiKey: IHEDVFKTRWHPDF-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  zirconium chloride-tetrahydrofuran 、 2,7-di(2,6-diisopropylphenyl)imino-1,8-di(trimethylsiloxy)naphthalene 以 二氯甲烷 为溶剂， 生成 FI(2)-Zr2
  参考文献：
  名称：

  Synthesis, Characterization, and Marked Polymerization Selectivity Characteristics of Binuclear Phenoxyiminato Organozirconium Catalysts

  摘要：

  The new binuclear phenoxyiminato zirconium complex {1,7-(O)(2)C10H4-2,7-[CH=N(2,6(t)Pr(2)C(6)H(3))] 2}Zr2Cl6(THF)(2)(Fl(2)-Zr-2) polymerizes ethytene with greater activity (similar to 8(x)) than the mononuclear analogue. Also, this catalyst produces high molecular weight ethylene + 1-hexene copolymers, while the mononuclear analogue yields only traces of copolymer under identical conditions. This ability to produce copolymers suggests cooperativity between the two Zr centers which promotes 1-hexene co-enchainment.

  DOI：

  10.1021/ja076857e