[indium(III)(N-(pyridine-2-ylmethyl)-2-oxy-benzylideneamine)2](perchlorate) | 1201811-61-1

• 英文名称: [indium(III)(N-(pyridine-2-ylmethyl)-2-oxy-benzylideneamine)2](perchlorate)
• CAS: 1201811-61-1
• 化学式: C₂₆H₂₂InN₄O₂*ClO₄
• 分子量: 636.757
• InChiKey: HZKHRSPIOPLSDI-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  indium nitrate hydrate 、 sodium perchlorate 、 2-((pyridin-2-ylmethylimino)methyl)phenol 在 三乙胺 作用下， 以 甲醇 为溶剂， 以57%的产率得到[indium(III)(N-(pyridine-2-ylmethyl)-2-oxy-benzylideneamine)2](perchlorate)
  参考文献：
  名称：

  Complexation of Group IIIA metals with asymmetric tridentate ligands: Synthesis, characterization, formation constants and cytotoxicity

  摘要：

  A series of new aluminum(III), gallium(III) and indium(III) complexes with some tridentate Schiff base, viz., N-{pyridine-2-ylmethyl}-2-hydroxy-5-methoxy-benzylideneamine [HL1], N-{pyridine-2-ylmethyl}-2-hydroxy-benzylideneamine [HL2], N-{pyridine-2-ylmethyl}-2-hydroxy-5-nitro-benzylideneamine [HL3], N-{pyridine-2-ylmethyl}-2-hydroxy-5-bromo-benzylideneamine [HL4], N-{pyridine-2-ylethyl}-2-hydroxy-5-methoxy-benzylideneamine [HL5], N-{pyridine-2-ylethyl}-2-hydroxy-benzylideneamine [HL6], N-{pyridine-2-ylethyl}-2-hydroxy-5-nitro-benzylideneamine [HL7], N-{pyridine-2-ylethyl}-2-hydroxy-5-bromo-benzylideneamine [HL8], with the general formula [ML2][Y] (M = Al3+, Ga3+, In3+; Y = NO3, ClO4) were synthesised and characterized by elemental analysis, H-1 NMR, FT-IR, UV-Vis spectrophotometry and mass spectrometry. The thermodynamic formation constants of the complexes were determined spectrophotometrically at constant ionic strength (I = 0.10 M NaClO4) and at 25 degrees C in methanol. The trend of formation constants of the complexes are as follow:Al < Ga < In5-OMe > 5-H > 5-NO2 > 5-BrAlso, their cytotoxic activities were evaluated in four various cell lines which showed their moderate cytotoxic effect. (c) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.07.021