| 1092983-83-9

• CAS: 1092983-83-9
• 化学式: C₅₆H₄₆Cu₂N₂O₈
• 分子量: 1002.08
• InChiKey: NETZPINNGNJZNN-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(2-hydroxyphenyl)-4,4-diphenyl-1,2-dihydro-4H-3,1-benzoxazine 、 copper diacetate 以 乙醇 为溶剂， 以87%的产率得到
  参考文献：
  名称：

  The copper(II) acetate complex with 2-(2-Hydroxyphenyl)-4,4-diphenyl-1,2-dihydro-4H-3,1-benzoxazine

  摘要：

  The Cu(II) acetate complex with 2-(2-hydroxyphenyl)-4,4-diphenyl-1,2-dihydro-4H-3,1-benzoxazine (L) was synthesized for the first time and structurally studied by X-ray diffraction. The complex crystallizes as two crystallographically independent centrosymmetric binuclear molecules [Cu-2(mu-L)(2)Ac-2] of similar structure, where L occurs as azomethin tautomeric form. The ligand performs tridentate chelate-bridging function. Each Cu atom exhibits extended tetragonal-pyramidal coordination by two O atoms and the N atom of one ligand L in the equatorial plane and by the O atom of the second ligand L in the axial position. The fourth equatorial position in the metal coordination polyhedron is occupied by the O atom of monodentate terminal acetate group.

  DOI：

  10.1134/s1070328407090096