[Fe2(CO)3(PPh3)(κ2-phenanthroline)(μ-SC3H6S)(μ-H)](1+) | 1228385-08-7

• 英文名称: [Fe2(CO)3(PPh3)(κ2-phenanthroline)(μ-SC3H6S)(μ-H)](1+)
• CAS: 1228385-08-7
• 化学式: C₃₆H₃₀Fe₂N₂O₃PS₂
• 分子量: 745.446
• InChiKey: WJNYYRDKRBZASN-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  四氟硼酸-二乙醚络合物 、 [Fe2(CO)3(PPh3)(κ2-phenanthroline)(μ-SC3H6S)]*CH2Cl2 以 二氯甲烷-D2 为溶剂， 生成 [Fe2(CO)3(PPh3)(κ2-phenanthroline)(μ-SC3H6S)(μ-H)](1+)
  参考文献：
  名称：

  Investigation on the Protonation of a Trisubstituted [Fe₂(CO)₃(PPh₃)(κ²-phen)(μ-pdt)] Complex: Rotated versus Unrotated Intermediate Pathways

  摘要：

  The substitution of PPh3 for a carbonyl group at the {Fe(CO)(3)} moiety in [Fe-2(CO)(4)(kappa(2)-phen)(mu-pdt)] results in the formation of the trisubstituted complex [Fe-2(CO)(3)(PPh3)(kappa(2)-phen)(mu-pdt)] (2). Unlike its tetracarbonyl precursor, the protonation of 2 at low temperature does not afford any apparent transient terminal hydride species. Hydride formation for [Fe-2(CO)(3)(L)(kappa(2)-phen)(mu-pdt)] (L = PPh3, CO) species is also studied by density functional theory calculations, which show that activation barriers to give terminal and bridging hydrides can be remarkably close for this class of organometallic compounds.

  DOI：

  10.1021/ic100108h