[Zn(4-(3-(1,2,4-triazolyl)-1,2,4-triazole))2(H2O)4]fluorosilicate | 956336-67-7

• 英文名称: [Zn(4-(3-(1,2,4-triazolyl)-1,2,4-triazole))2(H2O)4]fluorosilicate
• CAS: 956336-67-7
• 化学式: C₈H₁₆N₁₂O₄Zn*F₆Si
• 分子量: 551.759
• InChiKey: IRIBXQDSWCSCIW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氟硅酸锌 、 3,4'-bis-1,2,4-1H-triazole 以 水 为溶剂， 以28%的产率得到[Zn(4-(3-(1,2,4-triazolyl)-1,2,4-triazole))2(H2O)4]fluorosilicate
  参考文献：
  名称：

  The syntheses, structures and fluorescent properties of two 3-D hydrogen-bonded frameworks constructed from monomeric Zn(II) and Cd(II) assemblies containing bitriazole

  摘要：

  Two monomeric Cd(II) and Zn(II) complexes [M(trtr)(2)(H2O)(4)](SiF6) (M = Cd for 1; Zn for 2) were obtained from the reactions of bitriazole ligand 4-[3-(1,2,4-triazolyl)-1,2,4-triazole] with metal fluorosilicate. 3-D supramolecular frameworks are constructed by the hydrogen bondings between the monomeric assemblies and SiF62-. The fluorescence of 1 and 2 feature the emission peaks at 454 and 348 run, respectively, originating from the pi-pi* intraligand transition and LMCT, which are related to the triazole rings the metal centers coordinate with. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.10.028