[ZnBr2(2-[2-(1-pyridin-2-ylethylideneamino)ethylamino]ethanol)] | 1314023-55-6

• 英文名称: [ZnBr2(2-[2-(1-pyridin-2-ylethylideneamino)ethylamino]ethanol)]
• CAS: 1314023-55-6
• 化学式: C₁₁H₁₇Br₂N₃OZn
• 分子量: 432.473
• InChiKey: DIFYBTLCKHSIHW-SAOBJNJYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-((1-(pyridine-2-yl)ethylideneamino)ethylamino)ethanol 、 zinc dibromide 以 甲醇 为溶剂， 以72%的产率得到[ZnBr2(2-[2-(1-pyridin-2-ylethylideneamino)ethylamino]ethanol)]
  参考文献：
  名称：

  Synthesis and Crystal Structures of Bromido-Coordinated Zinc(II) and Copper(II) Complexes with Schiff Bases

  摘要：

  Two new mononuclear bromido-coordinated complexes, [ZnBr2L1] (1) and [CuBr2L2] (2), where L-1 = 2-[2-(1-pyridin-2-ylethylideneamino)ethylamino] ethanol and L-2 = N'-(1-pyridin-2-ylethylidene) ethane-1,2-diamine, have been synthesized and structurally characterized by IR spectra and X-ray crystallography. Complex (1) crystallizes in the orthorhombic space group Pbca with unit cell dimensions a = 15.146(3) angstrom, b = 11.400(2) angstrom, c = 17.350(3) angstrom, V = 2995.7(9) angstrom(3), Z = 8, R-1 = 0.0469, and wR(2) = 0.0909. Complex (2) crystallizes in the monoclinic space group P2(1)/n with unit cell dimensions a = 9.041(1) angstrom, b = 14.994(2) angstrom, c = 9.202(1) angstrom, beta = 99.352(3)degrees, V = 1230.8(3) angstrom(3), Z = 4, R-1 = 0.0290, and wR(2) = 0.0580. The Zn atom in (1) is five-coordinate in a trigonal-bipyramidal geometry, and the Cu atom in (2) is five-coordinate in a square pyramidal geometry.

  DOI：

  10.1080/15533174.2011.568462