| 168097-22-1

• CAS: 168097-22-1
• 化学式: C₄₂H₆₅Al₃N₂O₂
• 分子量: 710.935
• InChiKey: WAYNCGIJNNPKSF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-bis(o-hydroxbenzyl)-1,2-diamino-4,5-dimethylbenzene 、 三异丁基铝 以 甲苯 为溶剂， 以96%的产率得到
  参考文献：
  名称：

  Trimetallic Aluminum and Gallium Alkyl Complexes with Tetradentate (N2O2) Ligands

  摘要：

  The present work describes the synthesis and characterization of a series of complexes of formula LAIR(AlR(2))(2) (R = Et, L = Salean (1), Salpan (2), Salophan (3), Salomphan (4); R = (i)Bu, L = Salean (5), Salpan (6), Salophan (7), Salomphan (8)). The use of the comparatively bulky (i)Bu group in 5 results in a complex which adopts a cis ligand configuration as shown by an X-ray structural analysis. The trimetallic complexes display H-1 NMR spectra that are consistent with a rigid solution-state geometry. The presence of a deshielding interaction between the protons on the alkyl group 13 reagent and the arylamine backbones of the Salophan and Salomphan ligands will be discussed. Additionally, the crystal structures of SalophanGaMe(GaMe(2))(2) (9) and SalomphanGaMe(GaMe(2))(2) (10) are reported.

  DOI：

  10.1021/om00008a052