[(2,2'-bipyridine)Ni(dimethyl 3-methyl-3-tert-butyl-1-cyclopropene-1,2-dicarboxylate)] | 343986-76-5

• 英文名称: [(2,2'-bipyridine)Ni(dimethyl 3-methyl-3-tert-butyl-1-cyclopropene-1,2-dicarboxylate)]
• CAS: 343986-76-5
• 化学式: C₂₂H₂₆N₂NiO₄
• 分子量: 441.149
• InChiKey: BMEYIMBVNLSWNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (2,2'-联吡啶)(1,5-环辛二烯)镍 、 dimethyl 3-tert-butyl-3-methyl-cyclopropene-1,2-dicarboxylate 以 not given 为溶剂， 生成 [(2,2'-bipyridine)Ni(dimethyl 3-methyl-3-tert-butyl-1-cyclopropene-1,2-dicarboxylate)]
  参考文献：
  名称：

  The First Crystal Structure of a Nickel Cyclopropene Complex

  摘要：

  Nikel(0) cyclopropene complexes are usually only detected as reactive intermediates during the oxidative cyclization of cyclopropenes at the Ni(0) site. In contrast, it was possible to isolate and structurally characterize such a Ni(0) cyclopropene complex: from the reaction of [(bipy)Ni(COD)] with dimethyl 3-methyl-3-tert-butyl-1-cyclopropene-1,2-dicarboxylate.

  DOI：

  10.1021/om0010971