[Me2In(2-pyrazine carboxylate)]2 | 953412-46-9

• 英文名称: [Me2In(2-pyrazine carboxylate)]2
• CAS: 953412-46-9
• 化学式: C₁₄H₁₈In₂N₄O₄
• 分子量: 535.961
• InChiKey: BHARIPQUGORWLR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-甲酸吡嗪 、 Trimethylindium-etherat 以 苯 为溶剂， 以97%的产率得到[Me2In(2-pyrazine carboxylate)]2
  参考文献：
  名称：

  Diorgano-gallium and -indium complexes with N-heterocyclic carboxylic acids: Synthesis, characterization and structures of [Me2M(O2C–C5H4N)]2, M=Ga or In

  摘要：

  The reaction of triorgano-gallium and -indium etherate with heterocyclic carboxylic acids in benzene at room temperature yields complexes of the type [R2M(L)](n)(M = Ga or In; R = Me or Et; L = 2-(C5H4N)CO2, 2-(C4H3N2)CO2 or 2-(C9H6N)CO2). These complexes have been characterized by elemental analysis, IR, UV-vis, NMR (H-1 and C-13{H-1}) and mass spectral data. Complexes with L = (C5H4N)CO2- and (C9H6N)CO2- showed photoluminescence on excitation with similar to 250 or similar to 310 nm radiation, respectively. Single crystal X-ray structural analysis of [Me2M(O2C-C5H4N-2)](2) (M = Ga or In), revealed a dimeric structure with five-coordinate metal atoms arising from the presence of two tridentate bridging picolinate ligands. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.06.065