bis{2-{[3-(but-3-enyloxy)phenylimino]methyl}-6-tert-butylphenoxy}titanium(IV) dichloride | 1404461-04-6

• 英文名称: bis{2-{[3-(but-3-enyloxy)phenylimino]methyl}-6-tert-butylphenoxy}titanium(IV) dichloride
• CAS: 1404461-04-6
• 化学式: C₄₂H₄₈Cl₂N₂O₄Ti
• 分子量: 763.64
• InChiKey: STUFYPAUDMWOIB-ODUVTEHGSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二异丙氧基二氯化钛 、 C₂₁H₂₅NO₂ 以 二氯甲烷 、 甲苯 为溶剂， 反应 24.0h， 生成 bis{2-{[3-(but-3-enyloxy)phenylimino]methyl}-6-tert-butylphenoxy}titanium(IV) dichloride
  参考文献：
  名称：

  Multicentered self-immobilized ethylene polymerization catalysts based on functionalized titanium halide salicylaldiminate complexes for the synthesis of ultra-high-molecular-weight polyethylene

  摘要：

  Specific features of ethylene polymerization using a new group of catalytic systems based on ten methylalumoxane-activated titanium halide salicylaldiminato complexes functionalized with omega-vinylalkoxy groups and containing tert-butyl substituents in the phenoxide moiety were studied. The catalytic activity of the new group of activated complexes is strongly affected by the position of the omega-vinylalkoxy functional group and by the number and position of substituents in the phenoxide moiety. These factors determine the ratio of the homogeneous and heterogeneous steps of the polymerization as a result of the catalyst self-immobilization onto the polymer formed, and also the molecular characteristics of the polymer obtained at 20, 40, and 60 degrees C and ethylene pressure of 0.4 MPa. The possibility and conditions of preparing ultra-high-molecular-weight polyethylene with improved morphology were revealed.

  DOI：

  10.1134/s1070427212090170