摩熵化学
数据库官网
小程序
打开微信扫一扫
首页 分子通 化学资讯 化学百科 反应查询 关于我们
请输入关键词

(cyclopentadienyl)RuCl(=CPh(p-MeC6H4))(PPh3) | 168064-08-2

中文名称
——
中文别名
——
英文名称
(cyclopentadienyl)RuCl(=CPh(p-MeC6H4))(PPh3)
英文别名
——
(cyclopentadienyl)RuCl(=CPh(p-MeC6H4))(PPh3)化学式
CAS
168064-08-2
化学式
C37H32ClPRu
mdl
——
分子量
644.158
InChiKey
FSDNJSQEXIFGDE-UHFFFAOYSA-M
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    None
  • 重原子数:
    None
  • 可旋转键数:
    None
  • 环数:
    None
  • sp3杂化的碳原子比例:
    None
  • 拓扑面积:
    None
  • 氢给体数:
    None
  • 氢受体数:
    None

反应信息

  • 作为产物:
    描述:
    (cyclopentadienyl)Ru(η(2)-O2CMe)(PPh3) 、 (4-methylphenyl)phenyldiazomethane甲苯 为溶剂, 以72%的产率得到(cyclopentadienyl)RuCl(=CPh(p-MeC6H4))(PPh3)
    参考文献:
    名称:
    Cyclopentadienyl— und Pentamethylcyclopentadienyl—Rutheniumkomplexe mit Carboxylat-, Vinylester- und Carben-Liganden
    摘要:
    Monomeric carboxylatoruthenium(II) complexes [C5R5Ru(eta(2)-O2CR')(PPh3)] (R = H, Me; R' = Me, Bu-t, CF3) were prepared by ligand displacement from [(C5R5)Ru(eta(3)-2-MeC3H4)(PPh3)] and R'CO2H. From a similar route, the tosylato and pentachlorphenolato derivatives [C5H5Ru{O2SO(p-C6H4Me)}(PPh3)](n) and [C5H5Ru(eta(2)-OC6Cl5)(PPh3)] were obtained. On treatment with PhNH2, CO, PPh3 and O-2, they reacted to give the complexes [C5H5Ru{O2SO(p-C6H4Me)}(L)(PPh3)] and [C5H5Ru(OC6Cl5(CO)(PPh3)] respectively. The reaction of [C5R5Ru(eta(2)-O2CRt)(PPh3)] (R' = Me, Bu-t) with terminal alkynes HC=CR (R = CO2Me, Ph) yielded the vinylesterruthenium(II) compounds [C5H5Ru(kappa(2)(C,O)-C(=CHR)OC(R')=O}(PPh3)] for which a resonance structure involving a carboxylato(vinylidene) species is postulated. The carbene half-sandwich type complexes [C5H5RuCl(=CRR')(PPh3)] (R and R' = C6H4X) were prepared in two steps from [C5H5Ru(eta(2)-O2CMe)(PPh3)], N2CRR' and either Al2O3/Cl- or Et3NHCl. The molecular structure of [C5Me5Ru(eta(2)-(O2CBu)-Bu-t)(PPh3)] and [C5H5RuCl(=CPh2)(PPh3)] have been determined by X-ray single-crystal structural investigations.
    DOI:
    10.1016/s0022-328x(97)00045-4
点击查看最新优质反应信息

文献信息

  • Braun, Thomas; Gevert, Olaf; Werner, Helmut, Journal of the American Chemical Society, 1995, vol. 117, # 27, p. 7291 - 7292
    作者:Braun, Thomas、Gevert, Olaf、Werner, Helmut
    DOI:——
    日期:——
查看更多