| 148480-67-5

• CAS: 148480-67-5
• 化学式: C₆₀H₄₂Mo₂N₄O₆P₂
• 分子量: 1168.84
• InChiKey: IRGZQTRRQWJPAI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,3-bis(2-pyridyl)quinoxaline molybdenumtetracarbonyl 在 CH₃CN 、 P(C₆H₅)3 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Synthesis of mono- and binuclear [{Mo(CO)3L}n(dpq)] [n = 1,2; L = CO, MeCN, PPh3; dpq = 2,3-bis(2-pyridyl)quinoxaline] complexes and heterobimetallic adduct formation with hexafluoroacetylacetonatecobalt(II)

  摘要：

  The new compounds [{MO(CO)4}n(dpq)] [n = 1,2; dpq = 2,3-bis(2-pyridyl) quinoxaline] on refluxing in MeCN produce the acetonitrile complexes [{Mo(CO)3 (NCMe)}n(dpq)] (n = 1,2). These acetonitrile derivatives behave as precursors for the tricarbonyl-based fragments [{MO(CO)3}n(dpq)] (n = 1,2); they react in CH2Cl2 at room temperature with PPh3 to afford the [{Mo(CO)3(PPh3)}n(dpq)] (n = 1,2) complexes. In addition, the ligating properties of the novel mononuclear products [Mo(CO)4(dpq)] and [Mo(CO)3(PPh3)(dpq)] towards [Co(hfacac)2] are also reported. The new substances were characterized by IR and electronic spectroscopy.

  DOI：

  10.1016/s0277-5387(00)87049-7