trans-Pt(SC6H4-4-Me)(Cl)(P(C6H4-4-Me)3)2 | 877611-58-0

• 英文名称: trans-Pt(SC6H4-4-Me)(Cl)(P(C6H4-4-Me)3)2
• CAS: 877611-58-0
• 化学式: C₄₉H₄₉ClP₂PtS
• 分子量: 962.475
• InChiKey: YEDPWWHONPMZDU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cis-dichlorobis(para-tolylphosphine)platinum 、 4-甲苯硫酚 在 pyridine 作用下， 以 正己烷 为溶剂， 以53%的产率得到trans-Pt(SC6H4-4-Me)(Cl)(P(C6H4-4-Me)3)2
  参考文献：
  名称：

  cis-to-trans Isomerization Promoted by Pyridine as a Crucial Step for the Selective Preparation of trans-Pt(SAr)(Cl)(PAr‘₃)₂

  摘要：

  The general strategy for the syntheses of trans-Pt(SAr)(Cl)(PAr'(3))(2) (1) (Ar = Ph, C6H4-2-Me, C6H4-3-OMe C(6)H(4-)2-F, etc.; Ar' = Ph, C6H4-4-OMe, C6H4-4-Me, and C6H4-4-CF3) by the reaction of cis-PtCl2(PAr'(3))(2) with ArSH has been developed. The mechanistic investigation suggested that isomerization of cis-1 into trans-1 promoted by the combined use of C6H6 as a solvent and pyridine as a base was the key to the successful preparation of 1.

  DOI：

  10.1021/ic051780l